a b s t r a c tArchitectured Ni-based superalloy scaffolds were fabricated by three-dimensional weaving of ductile Ni20Cr (wt.%) wires followed by gas-phase alloying with aluminum and titanium via pack cementation. Bonding of neighboring wires occurs at necks that are formed by solid-state diffusion or by formation of a transient-liquid phase. Three-point bending tests of the superalloy weaves, after homogenization and aging to achieve a c/c 0 structure, show that, as bonding between wires increases, the materials withstand higher stresses and strains before onset of damage.Architectured cellular materials [1][2][3][4][5][6][7][8], such as honeycombs [4], trusses [5], and wire-based structures [6][7][8], offer a combination of low density and high specific strength, stiffness, permeability, and surface area. These materials have periodic structures that can be designed by using topological optimization models to enhance the desired properties [9-11]. One example is 3D woven metal structures, fabricated from Cu or Ni-Cr wires, that are topologically optimized to provide improved permeability in preferred directions with minimal loss in stiffness for thermo-structural applications [8]. Such cellular materials are of interest for extreme environments, since increased permeability allows for active cooling and results in prolonged service life, or even enables material use, at elevated service temperatures and stresses. A number of studies have been published in the area of periodic cellular nickel-based superalloys, none, however, using topological optimization tools [12][13][14]. The main reason for the limited number of existing studies is the difficulty in the processing of such superalloy architectured structures. Particularly, processing of wire-based structures are very challenging due to three manufacturing obstacles: (i) superalloy wires, especially below 500 lm diameter, are difficult to draw, and hence not widely available through suppliers, (ii) if drawn, they are not sufficiently ductile to withstand the bending angles required for weaving, and (iii) if woven, the contact points must be bonded to reach the full potential of mechanical properties, which is difficult due to the presence of oxide layers at the wire surface and low diffusivity, limiting the extent of solid-state bonding.In a recent study, we reported the fabrication of topologically optimized Ni-Cr-Al superalloy structures produced using 3D textile processes [7,8]. Ni-20Cr (all compositions are given in wt.% hereafter) wires were 3D woven or 3D braided, taking advantage of the room-temperature ductility of these wires, and subsequently aluminized via pack cementation [7], a chemical vapor deposition process that has been widely used to create aluminide coatings on Ni-based superalloys for corrosion protection [15][16][17]. Aluminized 3D woven structures were then homogenized into Ni-Cr-Al alloys and aged for the precipitation of c 0 particles, which are responsible for the high temperature creep resistance of superalloys. Simultaneously, the...