Cracks in reinforced concrete provide preferential access for aggressive substances into the concrete. Therefore, the corrosion of reinforcement bars is accelerated. Besides, carbonation, sulfate attack, and alkali-silicate reaction take place deep inside the concrete. Fortunately, from previous experiments, it was found that cracks in concrete can be healed with water and Ca is a main chemical element of the reaction products of self-healing. However, the ion concentrations in water can be various depending on the sources of water. There is still a lack of information on the effect of ion concentrations on selfhealing. In this article, the effect of Ca 2+ ions on self-healing was investigated experimentally. Ca(OH) 2 was added into water as a healing agent. Self-healing behavior of cracks with saturated Ca(OH) 2 solution was explored and compared with that with distilled water. In order to gain deeper insight into the mechanism, the reaction products of self-healing were characterized by energy-dispersive spectroscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis. In addition, the filling fraction of cracks as a function of time was determined by means of backscattered electron image analysis. The efficiency of self-healing induced by saturated Ca(OH) 2 solution was evaluated and compared with that with distilled water.