Permeation and concentration of compactin by a liquid membrane technique

Ishizu, Hiroshi; Habaki, Hiroaki; Kawasaki, Junjiro

doi:10.1016/s0376-7388(02)00528-8

Cited by 13 publications

(4 citation statements)

References 12 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Indeed, Kawasakia et al [15] studied the extraction of an antibiotic "Erythromycin A" from a diluted alkaline aqueous solution using a SLM containing 1-decanol as carrier. Also, Ishizu et al [16] used a SLM containing di-n-octylamine as carrier diluted in toluene or mesitylene as organic phase to achieve the extraction of "compactin" active ingredient from a diluted aqueous solution. Kouki et al [17] studied the feasibility of the extraction of salicylic acid from acidic aqueous solution using a SLM containing aliquat-336 ionic liquid as carrier diluted in 2-octanol as organic phase.…”

Section: Introductionmentioning

confidence: 99%

Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Kamal¹

2017

AJCHE

View full text Add to dashboard Cite

Transport of lysine acetylsalicylate (LAS) through supported liquid membrane was investigated using methyl cholate (MC) as extractive agent. Kinetic and thermodynamic models were developed, based on the interaction of the substrate LAS with the extractive agent T, and the diffusion of the formed entity (TS) through the membrane. The experimental results verify the models and enable the determination of macroscopic parameters (permeabilities (P) and initial fluxes (J 0 )), as well as microscopic parameters (association constants (K ass ), and apparent diffusion coefficients (D*)), relating to formed entity (TS) and its diffusion through the membrane organic phase. Parameters such as initial concentration of the substrate in the feed phase, pH of the feed and stripping phases and temperature of the extraction medium were studied. The results obtain indicate that the mechanism of the migration of LAS through the membrane organic phase cannot be a pure diffusion movement but it takes place by successive jumps from one site to another of the extractive agent, via interaction reactions with LAS.

show abstract

Section: Introductionmentioning

confidence: 99%

Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Kamal¹

2017

AJCHE

View full text Add to dashboard Cite

show abstract

“…The use of such membranes for the selective separation of different chemical species is a promising technique as an attractive alternative to others conventional solvent extraction techniques. The most widely studied processes for selective separation are metal ions [1][2][3] and acids [4][5][6][7] but neutral molecules, such as different drugs, 8,9 phenols, 10,11 and sugars [12][13][14] have also been studied. This SLM system offers substantial advantages including low cost, high efficiency, and minimum product contamination.…”

Section: Introductionmentioning

confidence: 99%

Understanding the influence of the ionic liquid composition and the surrounding phase nature on the stability of supported ionic liquid membranes

et al. 2011

View full text Add to dashboard Cite

in Wiley Online Library (wileyonlinelibrary.com).The industrial application of supported liquid membranes (SLMs) is still limited due to concerns about their stability. In a previous work, the selective separation of the substrates and products of a transesterification reaction was successfully carried out using Nylon membranes impregnated with ionic liquids (ILs). This article analyses the effect of both the IL composition and the nature of the surrounding phase on the stability of these SLMs to design highly stable supported ionic liquid systems. For this purpose, the stability of SLMs based on several ILs after immersion for a week in different feed/receiving phases was characterized using scanning electron microscopy combined with energy dispersive X-ray (SEM-EDX). The differential migration of the ILs observed from the membrane toward the surrounding phases was found to be correlated with the solubility of the ILs in the contacting phases. It was observed that SLM stability increased as the polarity of the solvent used as receiving phase decreased and as the hydrophilic character of the ILs used as liquid phase increased. Furthermore, the polymeric support was found to have a strongly stabilizing effect because losses of IL after immersion in a given surrounding phase were much lower than that derived from the solubility of the IL in this phase.

show abstract

“…The use of such membranes for the selective separation of different chemical species is a promising technique as an attractive alternative to others conventional solvent extraction techniques. The most widely studied processes for selective separation are metal ions1–3 and acids4–7 but neutral molecules, such as different drugs,8, 9 phenols,10, 11 and sugars12–14 have also been studied. This SLM system offers substantial advantages including low cost, high efficiency, and minimum product contamination.…”

Section: Introductionmentioning

confidence: 99%

Bis(azobenzene)‐Based Photoswitchable, Prochiral, C^α‐Tetrasubstituted α‐Amino Acids for Nanomaterials Applications

Fatás

Longo

Rastrelli

et al. 2011

Chemistry A European J

View full text Add to dashboard Cite

The industrial application of supported liquid membranes (SLMs) is still limited due to concerns about their stability. In a previous work, the selective separation of the substrates and products of a transesterification reaction was successfully carried out using Nylon membranes impregnated with ionic liquids (ILs). This article analyses the effect of both the IL composition and the nature of the surrounding phase on the stability of these SLMs to design highly stable supported ionic liquid systems. For this purpose, the stability of SLMs based on several ILs after immersion for a week in different feed/receiving phases was characterized using scanning electron microscopy combined with energy dispersive X‐ray (SEM‐EDX). The differential migration of the ILs observed from the membrane toward the surrounding phases was found to be correlated with the solubility of the ILs in the contacting phases. It was observed that SLM stability increased as the polarity of the solvent used as receiving phase decreased and as the hydrophilic character of the ILs used as liquid phase increased. Furthermore, the polymeric support was found to have a strongly stabilizing effect because losses of IL after immersion in a given surrounding phase were much lower than that derived from the solubility of the IL in this phase. © 2011 American Institute of Chemical Engineers AIChE J, 2012

show abstract

Permeation and concentration of compactin by a liquid membrane technique

Cited by 13 publications

References 12 publications

Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Understanding the influence of the ionic liquid composition and the surrounding phase nature on the stability of supported ionic liquid membranes

Bis(azobenzene)‐Based Photoswitchable, Prochiral, C^α‐Tetrasubstituted α‐Amino Acids for Nanomaterials Applications

Contact Info

Product

Resources

About

Permeation and concentration of compactin by a liquid membrane technique

Cited by 13 publications

References 12 publications

Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Facilitated Transport of Lysine Acetylsalicylate Through Supported Liquid Membrane Using Methyl Cholate as Carrier: Parameters and Mechanism

Understanding the influence of the ionic liquid composition and the surrounding phase nature on the stability of supported ionic liquid membranes

Bis(azobenzene)‐Based Photoswitchable, Prochiral, Cα‐Tetrasubstituted α‐Amino Acids for Nanomaterials Applications

Contact Info

Product

Resources

About

Bis(azobenzene)‐Based Photoswitchable, Prochiral, C^α‐Tetrasubstituted α‐Amino Acids for Nanomaterials Applications