Permittivity and density of binary systems of {dimethyl or diethyl carbonate}+n-dodecane from K

Rivas, M.A.; Pereira, S.M.; Banerji, Natalie; Iglesias, T.P.

doi:10.1016/j.jct.2003.11.007

Cited by 30 publications

(14 citation statements)

References 30 publications

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“…In order to define better the thermophysical properties of 2,5,8,11,14-pentaoxapentadecane or tetraglyme with other components and within the framework of the investigation on the determination of thermophysical properties of binary liquid mixtures containing (glymes + n-alkanes or organic carbonates) [25][26][27][28][29], we report in this paper experimental relative permittivity, e, at frequency 1 MHz, and density on mixing, q, over the whole composition range at T = (288. 15, 298.15, 308.15, 318.15, and 328.15) K for the binary mixtures 2,5,8,11,14-pentaoxapentadecane or {tetraglyme + dimethyl (DMC) or diethyl carbonate (DEC)} at atmospheric pressure.…”

Section: Introductionmentioning

confidence: 99%

On permittivity and density of the systems (tetraglyme+dimethyl or diethyl carbonate) and the formulation of Δε in terms of volume or mole fraction

Rivas

Iglesias

2007

The Journal of Chemical Thermodynamics

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Section: Introductionmentioning

confidence: 99%

On permittivity and density of the systems (tetraglyme+dimethyl or diethyl carbonate) and the formulation of Δε in terms of volume or mole fraction

Rivas

Iglesias

2007

The Journal of Chemical Thermodynamics

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“…The density, ρ, and viscosity, η, of multicomponent mixtures are required in many chemical and environmental engineering calculations involving fluid flow, heat, and mass transfer (Giro et al, 2003). The dielectric constant (relative permittivity) provides important information about intermolecular, structural, and energy interactions in the liquid state (Rivas et al, 2004).…”

Section: Properties Of Mixed Solventsmentioning

confidence: 99%

“…Other equations are also available in the literature (e.g., Pandey and Sanguri, 2001;Rivas et al, 2004).…”

Section: )mentioning

confidence: 99%

Solution Properties of Inorganic Contamination in Mixed Solvents: Theory, Progress, and Limitations

Srour¹,

McDonald

2011

Critical Reviews in Environmental Science and Technology

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Most of what is known about the environmental fate and transport of contaminants comes from studies of dilute, aqueous solutions. Theoretical and practical aspects of hydrophobic organic contaminants in aqueous mixtures of organic solvents are well developed, but relatively little attention has been paid to those situations where inorganic contaminants such as metals, water, and organic solvents occur simultaneously. The authors discuss changes in solution properties accompanying the addition of organic solvents. They review more than 500 references to available data on ion solvation, solubility, activity, acidity, pairing, and pH in electrolyte and electrolyte-free solvent mixtures and tabulate selected experimental values. Whenever available, equations developed to estimate these properties are given and their applications and limitations described. The implications of the progress in mixed-solvents solution chemistry on contaminant behavior and transport are described. Major limitations to the study of inorganic contamination in mixed solvents include the absence of complete and comprehensive data (e.g., type of ionic species, activity coefficients, solubility constants) that characterize solute and solvent properties in these mixtures and the indefinite number of possible solute and solvent combinations. The generation of models predicting such data from easily measured benchmark solute and solvent properties is a major challenge. The availability of such database and models may open the field for environmental engineers and soil scientists to study the basic chemical processes and mechanisms of metal contamination in complex multicomponent systems.

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“…In order to better define the thermophysical properties of 2,5,8,11,14-pentaoxapentadecane or tetraglyme with other components and within the framework of the systematic investigation on the determination of thermophysical properties of binary liquid mixtures of interest to refrigeration industry [22][23][24][25][26][27] we report in this paper experimental relative permittivity, e, at frequency 1 MHz, and density on mixing, q, over the whole composition range at T = (288. 15, 293.15, 298.15, 303.15, 308.15, 318.15, and 328.15) K for the binary mixtures 2,5,8,11,14-pentaoxapentadecane or tetraglyme + (n-nonane or n-dodecane) at atmospheric pressure.…”

Section: Introductionmentioning

confidence: 99%

On the permittivity and density of the systems {tetraglyme+(n-nonane or n-dodecane)} at various temperatures

Rivas

Iglesias

Pereira

et al. 2006

The Journal of Chemical Thermodynamics

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Permittivity and density of binary systems of {dimethyl or diethyl carbonate}+n-dodecane from K

Cited by 30 publications

References 30 publications

On permittivity and density of the systems (tetraglyme+dimethyl or diethyl carbonate) and the formulation of Δε in terms of volume or mole fraction

On permittivity and density of the systems (tetraglyme+dimethyl or diethyl carbonate) and the formulation of Δε in terms of volume or mole fraction

Solution Properties of Inorganic Contamination in Mixed Solvents: Theory, Progress, and Limitations

On the permittivity and density of the systems {tetraglyme+(n-nonane or n-dodecane)} at various temperatures

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