2024
DOI: 10.1002/anie.202401590
|View full text |Cite
|
Sign up to set email alerts
|

Peroxygenase‐Enabled Reductive Kinetic Resolution for the Enantioenrichment of Organoperoxides

Qianqian Shen,
Juzhang Yan,
Yuchen Han
et al.

Abstract: Enantiomerically pure organoperoxides serve as valuable precursors in organic transformations. In this study, we present the first examples of unspecific peroxygenase‐catalyzed kinetic resolution of racemic organoperoxides through asymmetric reduction. Through meticulous investigation of the reaction conditions, it is shown that the unspecific peroxygenase from Agrocybe aegerita (AaeUPO) exhibits robust catalytic activity in the kinetic resolution reactions of the model substrate with turnover numbers up to 60… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Year Published

2024
2024
2024
2024

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
references
References 44 publications
0
0
0
Order By: Relevance