Abstract. Quasi-irreversible increase in the electrical conductivity is observed in single crystals of LaGa 1-x Mn x O 3. The effect lasts for long time at room temperature and can be erased by heating of the crystal above the phase transition temperature. We explain the observed effects in terms of ionization and local lattice distortion processes.PACS Codes/ Keywords: Manganites, Non-linear effects, Irreversibility, 72.20,
INTRODUCTIONIn the past few years, perovskite manganites (such as La 1-x Sr x MnO 3 , La 1-x Ca x MnO 3 , etc.) have attracted much scientific attention due to effect of the colossal magnetoresistance (CMR) effect and complex diagram of phase transitions in these materials [1]. As was recently reported, some low-doped manganites exhibit effect of irreversibility in transport and magnetic properties induced by optical illumination, thermal, electric or magnetic field cycling in the range of ferromagnetic transition [2][3][4][5][6][7]. These memory effects are explained with intrinsic coexistence of two or more phases with different magnetic and transport properties on the submicrometer scale and microstructural changes in the phases content. On the other hand, high-resistivity perovskite materials with very low concentration of Mn ions also exhibit interesting memory effects. Mn doped yttrium orthoaluminates, Mn:YAlO 3 , high-quality optical single crystals, demonstrate significant changes in color and photorefractive index induced by photo illumination [8,9]. These effects are quasipermanent, lasting for many years at room temperature, and completely erasable by heating the crystal up to ~ 230 C. To better understand the origin of the irreversibility in perovskites with different content of Mn ions, we have studied the series of LaGa 1-x Mn x O 3 with concentration of Mn ions varying from 2% to 100%. In contrast to the well-known manganite CMR systems, in our single crystal materials Mn ions are diluted by nonmagnetic Ga ions, which enter the same place in the crystal structure as Mn ions. As was reported earlier [10], the low-field conductivity of such systems can be described in terms of the small polaron hopping model. Here we mostly concentrate on non-linearity and irreversible effects observed in the electric conductivity.