Persistent microporosity of a non-planar porphyrinoid based on multiple supramolecular interactions for nanomechanical sensor applications

Chahal, Mandeep K.; Maji, Subrata; Liyanage, Anuradha; Matsushita, Yoshitaka; Hill, Pelin Jonathan; Payne, Daniel Tony; Jevasuwan, Wipakorn; Fukata, Naoki; Karr, Paul A.; Labuta, Jan; Shrestha, Lok Kumar; Ishihara, Shinsuke; Ariga, Katsuhiko; D’Souza, Francis; Yoshikawa, Genki; Yamauchi, Yusuke; Hill, Jonathan P.

doi:10.1039/d2qm01039a

“…(C, D) Crystalline materials in which porphyrin molecules are integrated into a nanoporous architecture through coordination interactions and chromophore π–π stacking, exhibiting persistent porosity and excellent sensing properties. Reproduced with permission [24b] . Copyright 2023 The Royal Society of Chemistry.…”

Section: Connection Of Nanoscale Components In Hybrid Nanoarchitecturesmentioning

confidence: 99%

Materials Space‐Tectonics: Atomic‐level Compositional and Spatial Control Methodologies for Synthesis of Future Materials

Eguchi

¹

,

Han²,

Hill

³

et al. 2023

Angew Chem Int Ed

Self Cite

4

0

View full text Add to dashboard Cite

Reactions occurring at surfaces and interfaces necessitate the creation of well‐designed surface and interfacial structures. To achieve a combination of bulk material (i.e., framework) and void spaces, a meticulous process of “nano‐architecting” of the available space is necessary. Conventional porous materials such as mesoporous silica, zeolites, and metal–organic frameworks lack advanced cooperative functionalities owing to their largely monotonous pore geometries and limited conductivities. To overcome these limitations and develop functional structures with surface‐specific functions, the novel materials space‐tectonics methodology has been proposed for future materials synthesis. This review summarizes recent examples of materials synthesis based on designing building blocks (i.e., tectons) and their hybridization, along with practical guidelines for implementing materials syntheses and state‐of‐the‐art examples of practical applications. Lastly, the potential integration of materials space‐tectonics with emerging technologies, such as materials informatics, is discussed.

show abstract

Materials Space‐Tectonics: Atomic‐level Compositional and Spatial Control Methodologies for Synthesis of Future Materials

Eguchi

¹

,

Han

²

,

Hill

³

et al. 2023

Angewandte Chemie

Self Cite

0

View full text Add to dashboard Cite

Reactions occurring at surfaces and interfaces necessitate the creation of well‐designed surface and interfacial structures. To achieve a combination of bulk material (i.e., framework) and void spaces, a meticulous process of “nano‐architecting” of the available space is necessary. Conventional porous materials such as mesoporous silica, zeolites, and metal–organic frameworks lack advanced cooperative functionalities owing to their largely monotonous pore geometries and limited conductivities. To overcome these limitations and develop functional structures with surface‐specific functions, the novel materials space‐tectonics methodology has been proposed for future materials synthesis. This review summarizes recent examples of materials synthesis based on designing building blocks (i.e., tectons) and their hybridization, along with practical guidelines for implementing materials syntheses and state‐of‐the‐art examples of practical applications. Lastly, the potential integration of materials space‐tectonics with emerging technologies, such as materials informatics, is discussed.

show abstract

Foldable polyimide/ionic liquid composite films with high transmittance and ultraviolet resistance benefiting from the intermolecular multipoint interaction

Chen,

Huang,

Zhang

et al. 2024

Chemical Engineering Journal

2

0

View full text Add to dashboard Cite

Persistent microporosity of a non-planar porphyrinoid based on multiple supramolecular interactions for nanomechanical sensor applications

Abstract: Porous substances such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolites are important materials for different applications, and several methods have been developed for their processing into device...

Cited by 5 publications

References 42 publications

Materials Space‐Tectonics: Atomic‐level Compositional and Spatial Control Methodologies for Synthesis of Future Materials

Materials Space‐Tectonics: Atomic‐level Compositional and Spatial Control Methodologies for Synthesis of Future Materials

Materials Space‐Tectonics: Atomic‐level Compositional and Spatial Control Methodologies for Synthesis of Future Materials

Foldable polyimide/ionic liquid composite films with high transmittance and ultraviolet resistance benefiting from the intermolecular multipoint interaction

Contact Info

Product

Resources

About