This study attempts to extend previous research on electrokinetic turbulence (EKT) in Oldroyd‐B fluid by investigating the relationship between the Weissenberg number () and the second‐order velocity structure function () under applied electric fields. Inspired by Sasmal's demonstration in Sasmal (2022) of how heterogeneous zeta potentials induce turbulence above a critical , we develop a mathematical framework linking to turbulent phenomena. Our analysis incorporates recent findings on AC (Zhao & Wang, 2017) and DC (Zhao & Wang 2019) EKT, which have defined scaling laws for velocity and scalar structure functions in the forced cascade region. Our finding shows that and , for a length scale , and , where is a velocity fluctuations quantity and denotes the time relaxation parameter. This work establishes a positive correlation between and turbulent flow phenomena through a rigorous analysis of velocity structure functions, thereby offering a mathematical foundation for building the design and optimization of EKT‐based microfluidic devices.