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As known, fracture's capacity and penetration are two key factors for fulfillment of the fracturing jobs including conventional and acid fracturing process. Penetration of acid into existing fractures can improve fracture capacity by etching of fracture surface. Increasing temperature of reservoir rock results in reduction of breakdown pressure. Thermo-gas-chemical technology by in-situ releasing of extra hot gases (N2 and steam) and acid provides a series of network with long fractures and permanent conductivity. A series of experiments in high-pressure and high-temperature (HPHT) reactor were designed to understand the performance and effectiveness of thermo-gas-chemical reaction and determine the optimum binary composition in order to release maximum temperature, pressure and acid generation to provide long conductive fractures. In parallel, dependence of breakdown pressure and temperature was modeled. Moreover, to understand the geometry and propagation of fractures, the effect of thermo-gas-chemical method was studied on core samples in core holder and then cores were scanned by 4D tomography. The preliminary results showed that during the thermo-gas-chemical reaction temperature in reaction zone reaches 207 ℃ and pressure 893 psi due to reaction products. It was found that reaction initiates just after the injection of activator and temperature and pressure increased instantly. This phenomenon acts as a strong impact to break formation rock. The pH of aqueous solutions during the reaction decreased from 8 to 1 and below which provides etching the surface of existing and new fractures. Observed that thermobaric parameters of reaction closely depend on the concentration and reaction activator. Experimental results show that the application of thermo-gas-chemical fluid instead of ordinary fracturing fluid, results in reduction of breakdown pressure from 3400 psi to 121 psi, due to induced thermobaric shock. Experiments on core samples and 4D tomography confirmed the formation of new fractures and expansion of existing ones. Thermo-gas-chemical technology by generation of in-situ hot gases and acid can provide a new high efficiency, cost-effective and eco-friendly method of EOR method for tight low permeability reservoirs and even depleted reservoirs without increasing water cut.
As known, fracture's capacity and penetration are two key factors for fulfillment of the fracturing jobs including conventional and acid fracturing process. Penetration of acid into existing fractures can improve fracture capacity by etching of fracture surface. Increasing temperature of reservoir rock results in reduction of breakdown pressure. Thermo-gas-chemical technology by in-situ releasing of extra hot gases (N2 and steam) and acid provides a series of network with long fractures and permanent conductivity. A series of experiments in high-pressure and high-temperature (HPHT) reactor were designed to understand the performance and effectiveness of thermo-gas-chemical reaction and determine the optimum binary composition in order to release maximum temperature, pressure and acid generation to provide long conductive fractures. In parallel, dependence of breakdown pressure and temperature was modeled. Moreover, to understand the geometry and propagation of fractures, the effect of thermo-gas-chemical method was studied on core samples in core holder and then cores were scanned by 4D tomography. The preliminary results showed that during the thermo-gas-chemical reaction temperature in reaction zone reaches 207 ℃ and pressure 893 psi due to reaction products. It was found that reaction initiates just after the injection of activator and temperature and pressure increased instantly. This phenomenon acts as a strong impact to break formation rock. The pH of aqueous solutions during the reaction decreased from 8 to 1 and below which provides etching the surface of existing and new fractures. Observed that thermobaric parameters of reaction closely depend on the concentration and reaction activator. Experimental results show that the application of thermo-gas-chemical fluid instead of ordinary fracturing fluid, results in reduction of breakdown pressure from 3400 psi to 121 psi, due to induced thermobaric shock. Experiments on core samples and 4D tomography confirmed the formation of new fractures and expansion of existing ones. Thermo-gas-chemical technology by generation of in-situ hot gases and acid can provide a new high efficiency, cost-effective and eco-friendly method of EOR method for tight low permeability reservoirs and even depleted reservoirs without increasing water cut.
Summary Nitrogen-generating systems (NGSs) are mainly used in the oil industry to fluidize low melting point organic deposits and gas hydrate buildups. They are exothermic reactions between two nitrogenous salts in acidic catalytic media. This work investigates the use of CO2 to promote NGS reactions instead of commonly used acids such as acetic and citric acids, which can be problematic for corrosion control. Sodium nitrite and ammonium chloride were the reactants, and CO2 performance was evaluated for up to 4 hours at 5 and 25°C, and either under autogenous pressure at 10, 25, and 50 bar of CO2 or pressurized at 10 bar of CO2 by adding 40 bar of nitrogen (totaling 50 bar). The nitrite conversion was determined by measuring the concentration of residual nitrite using titration. Thus, it was verified that the CO2 effectively promoted the NGS at various experimental conditions. The nitrite conversion increased with increasing CO2 pressure and increasing temperature. Moreover, the nitrite conversion was enhanced in the pressurized system (PS) because the high pressure enabled the dissolution of CO2 in the aqueous medium, and therefore, the constant formation of carbonic acid, favoring the acidic catalytic medium at the reaction. This advantage was confirmed by carrying out an NGS catalyzed by acetic acid, in which the pH increases as reagents are consumed, and therefore, a lower nitrite conversion is achieved. The use of CO2 also converts the NGS in a process more suitable for flow assurance applications in offshore oil production, particularly in the Brazilian presalt fields where the coproduced CO2 can be used.
While high working pressure and complex procedure restrict application of conventional foam fracturing, in-situ foam can overcome the limitations because it is liquid while pumping, reducing flow friction and dosage of special equipment. It gradually foams in the formation with large amount of heat released and pressure increased, improving flowback performance. Thus, this study developed an in-situ foam fracturing fluid stabilized by a novel microbial polysaccharide called diutan gum, evaluated its performance, and investigated its proppant suspension mechanism at high temperature. First, based on the foam comprehensive value, the polysaccharide stabilizer and foaming agent systems of N2 foam and CO2 foam were selected separately. Second, the self-generated N2 systems and self-generated CO2 systems were screened in terms of gas production efficiency and rate. Third, on the premise of meeting compatibility, the selected foam systems and self-generated gas systems were combined, and necessary additives were introduced to prepare in-situ N2 and in-situ CO2 foam fracturing fluid systems, respectively. The stability and foaming ability of in-situ foams were evaluated at high temperature, and the optimal ones were selected. Then, the proppant suspension performance, heat and shear resistance, and viscoelasticity of the optimal ones were evaluated at high temperature, and this study tailored a method for evaluating proppant suspension performance of the in-situ foam fracturing fluid due to its difference from the conventional ones. Finally, based on experimental data and rules, the proppant suspension mechanism of in-situ foam fracturing fluid at high temperature was revealed. The combination of diutan gum and AOS exhibited outstanding ability in enhancing the foam comprehensive value of both N2 and CO2 foam, and two kinds of CO2 foam and N2 foam systems with higher comprehensive values were selected respectively. The self-generated nitrogen and carbon dioxide systems with the highest gas production rate and efficiency were respectively selected, with the highest gas production efficiency reaching 95.9%. Thanks to these two excellent components, the in-situ N2foam volume reached 518mL which was 26 times of the base fluid of 20mL and remained 480mL within 90 minutes even at 70°C, demonstrating excellent foaming ability and foam stability. However, the stability of the in-situ CO2 foam was poor, as the foam volume dropped from 515mL to 250mL in just about 13 minutes. The in-situ N2 foam fracturing fluid obtained remarkable proppant suspension performance that with only 20mL of base fluid, it fully suspended 25mL of 70/140 mesh ceramic proppant for up to 120min, achieving proppant volume fraction as high as 55.6%. The in-situ CO2 foam could not even suspend 5mL of proppant, so it was eliminated and the in-situ N2 foam fracturing fluid was determined as the optimal system whose rheological properties was also extraordinary. After continuous shear for 2h at 70° and 170s−1, it maintained a viscosity of 59.4mPa·s, and it exhibited brilliant elasticity that its storage modulus was always greater than the loss modulus, ensuring its excellent proppant suspension performance. Ultimately, its proppant suspension mechanism was revealed in four stages. The results suggest that the in-situ foam fracturing fluid stabilized by diutan gum obtains promising applications and is supposed to be further studied.
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