The triblock copolymer poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (L64, PEO 13 PPO 30 PEO 13 ) in 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF 4 ]) can form lamellar liquid crystalline (L a ). The effect of apolar cyclohexane molecules on the L a phase was investigated by using polarized optical microscopy (POM) and small-angle x-ray scattering (SAXS). The results of POM and SAXS show that a suitable amount of cyclohexane can contribute to the formation of lamellar liquid crystals, and the ordering of L a phase is increased. For comparison, the effect of polar water on L a phase was explored. After adding water, both EO groups and [BF 4 ] -anion can form hydrogen bonds with water molecules, which weakens the electrostatic interactions between L64 and [Bmim] [BF 4 ] and therefore the ordering of lamellar structures is destroyed.