This
work reports phase equilibrium experimental data of binary
and ternary systems involving carbon dioxide (CO2), 5-(2-propenyl)-1,3-benzodioxole
(safrole), and ethenylbenzene (styrene). The experimental phase equilibrium
data were measured using a high-pressure variable-volume view cell
based on the static synthetic method in the temperature range of (303
to 343) K, at several CO2-overall compositions and pressures
up to 16 MPa. For ternary system measurements, solutions of safrole
and styrene with styrene mass fractions of 0.75 and 0.90 on CO2 free basis were prepared. The results showed that, in the
experimental range investigated, only vapor–liquid equilibria
(VLE) were detected with bubble (BP) and dew (DP) point transitions.
The experimental data were satisfactorily represented by the Peng–Robinson
equation of state (PR-EoS) with the classical quadratic mixing rules.
The EoS interaction parameters were fitted from binary systems and
then used to predict the phase behavior of the ternary system with
a good agreement.