Phase compatibility in the system CaOSiO2Al2O3Fe2O3SO3 referred to sulphoaluminate belite cement clinker

Sahu, Sadananda; Majling, J.

doi:10.1016/0008-8846(93)90070-p

Cited by 49 publications

(20 citation statements)

References 4 publications

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“…Patterns were recorded on an X'Pert MPD PRO diffractometer (PANalytical) in reflection geometry (θ/2θ) using strictly 7 monochromatic CuKα 1 radiation (λ=1.54059Å) [Ge(111) primary monochromator]. The X-ray tube worked at 45 kV and 40 mA.…”

Section: Laboratory X-ray Powder Diffraction (Lxrpd)mentioning

confidence: 99%

“…Cement nomenclature will be used hereafter: C=CaO, S=SiO 2 , A=Al 2 O 3 , F=Fe 2 O 3 , S=SO 3 , M=MgO, T=TiO 2 and H=H 2 O. In addition, other phases, such as C 2 S, CA, C 4 AF, CSH 2 , CSH 0.5 , CS, and so on, may also be present in their composition [7]. The main performances of these eco-cements are high early strength, fast setting time, good chemical resistance and, depending on the amount of the added sulfate, these cements can also be used as constituents of self-leveling materials [8,9,10,11].…”

Section: Introductionmentioning

confidence: 99%

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Tailored setting times with high compressive strengths in bassanite calcium sulfoaluminate eco-cements

García-Maté

Londoño-Zuluaga

Torre

et al. 2016

Cement and Concrete Composites

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This work deals with the hydration of a calcium sulfoaluminate (CSA) eco-cement prepared with bassanite and different additives (type and content) at a fixed water/CSA ratio of 0.5. Pastes prepared with bassanite show high water demands, high viscosity values and short initial setting times which are related to the fast dissolution rate of bassanite and the subsequent precipitation of gypsum. These facts have a dramatic effect onto the mechanical strength values, and make necessary the addition of additives.Here, the addition of different amounts of specific retarders (polycarboxylate, tartaric acid and phosphonic acid) not only improved the workability of pastes and mortars, but also delayed the setting time, by modifying the dissolution rates of the phase(s), and improved mechanical strengths.Finally, mortars with high compressive strengths (46 and 84 MPa at 1 and 7 days of hydration, respectively) and, chiefly, tailored setting times with high strengths have been prepared.

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Section: Laboratory X-ray Powder Diffraction (Lxrpd)mentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Tailored setting times with high compressive strengths in bassanite calcium sulfoaluminate eco-cements

García-Maté

Londoño-Zuluaga

Torre

et al. 2016

Cement and Concrete Composites

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“…Calcium sulfoaluminate (C 4 A 3 $) is one of the main constituents of a low-CO 2 alternative clinker [1][2][3][4], which possesses a rapid hydration rate and is the most abundant constituent of sulfoaluminate cement clinkers in marine engineering and waterproof engineering [5][6][7][8][9]. The substitution of Ba 2+ for Ca 2+ to improve the performance of C 4 A 3 $ has been reported [10][11][12][13].…”

Section: Introductionmentioning

confidence: 99%

EFFECT OF K₂O AND MgO ON THE FORMATION AND HYDRATION ACTIVITY OF Ba-BEARING CALCIUM SULFOALUMINATE

Shen¹

2016

Ceramics - Silikaty

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“…Recently, there has been a renewed interest in CSA cements because of their potential environmental benefits and performance advantages in special applications, and their rise in popularity has been accompanied with some state of the art reviews (2)(3)(4). The term CSA cements is usually reserved for those clinkers containing more than 50wt% of Klein's salt and they may also have minor amounts of phases such as C 2 S, CA, C 4 AF, CŜ , CŜ H 2 (5).…”

Section: Introductionmentioning

confidence: 99%

Effect of the strontium aluminate and hemihydrate contents on the properties of a calcium sulphoaluminate based cement

Velazco¹,

Almanza-Robles²,

Cortés³

et al. 2014

Mater. construcc.

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ABSTRACT:The effect of strontium aluminate (SrAl 2 O 4 ) on the hydration process of a calcium sulphoaluminate (C 4 A 3 Ŝ ) cement was investigated. Cement pastes were prepared by mixing C 4 A 3 Ŝ , hemihydrate (CaSO 4 ·½H 2 O, CŜ H 0.5 ) and 0, 10 or 20wt% of SrAl 2 O 4 (SrA). The amount of CŜ H 0.5 was 15, 20 or 25wt% based on the C 4 A 3 Ŝ quantity. The cement pastes were hydrated using water to cement ratios (w/c) of 0.4 and 0.5. Samples were cured from 1 to 28 d. The compressive strength and setting time were evaluated and the hydration products were characterized. It was found that the setting time was delayed up to 42 min for the samples containing SrAl 2 O 4 compared to samples without addition. The samples with 25wt% hemihydrate containing 20wt% SrAl 2 O 4 developed the highest compressive strength (60 MPa) after 28 d of curing. The main product after hydration was ettringite (C 6 AŜ 3 H 32 ). The morphology of this phase consisted of thin needle-shaped crystals. RESUMEN: Efecto del contenido de aluminato de estroncio y hemihidrato sobre las propiedades de un cemento de sulfoaluminato de calcio.Se investigó el efecto de la adición de aluminato de estroncio (SrAl 2 O 4 ) sobre las propiedades de un cemento de sulfoaluminato de calcio (C 4 A 3 Ŝ ). Se prepararon muestras mezclando C 4 A 3 Ŝ , hemihidrato (CaSO 4 ·½H 2 O, CŜ H 0.5 ) y 0, 10 o 20% e.p de SrAl 2 O 4 (SrA). La cantidad de CŜ H 0.5 fue de 15, 20 o 25% e.p. basado en la cantidad de C 4 A 3 Ŝ . Las relaciones agua/cemento utilizadas fueron 0.4 y 0.5. Las muestras fueron curadas hasta 28 d. Se evaluó el tiempo de fraguado y la resistencia a la compresión. Los productos de hidratación se caracterizaron mediante DRX y MEB. El tiempo de fraguado se retardó hasta 42 minutos con la adición del SrAl 2 O 4 comparado con las muestras sin adiciones. Las muestras con 25% e.p. de yeso y 20% e.p. de SrAl 2 O 4 desarrollaron la mayor resistencia a la compresión alcanzando 60 MPa a 28 d de curado. Los análisis por MEB y DRX muestran como principal producto de hidratación a la etringita (C 6 AŜ 3 H 32 ), cuya morfología se observa como cristales aciculares.

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Phase compatibility in the system CaOSiO2Al2O3Fe2O3SO3 referred to sulphoaluminate belite cement clinker

Cited by 49 publications

References 4 publications

Tailored setting times with high compressive strengths in bassanite calcium sulfoaluminate eco-cements

Tailored setting times with high compressive strengths in bassanite calcium sulfoaluminate eco-cements

EFFECT OF K₂O AND MgO ON THE FORMATION AND HYDRATION ACTIVITY OF Ba-BEARING CALCIUM SULFOALUMINATE

Effect of the strontium aluminate and hemihydrate contents on the properties of a calcium sulphoaluminate based cement

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