Phase-controlled synthesis of thermally stable nitrogen-doped carbon supported iron catalysts for highly efficient Fischer-Tropsch synthesis

Preparation of Nitrogen Doped Biochar-Based Iron Catalyst for Enhancing Gasoline-Range Hydrocarbons Production

“…(a) CO conversion and product selectivity of FTS results, (b) comparison of gasoline and C 5+ productivity results with previous works, − and (c) stability of the Fe/NDPC bio‑2 catalyst over a time on stream of 130 h.…”

Topotactic transformation of metal–organic frameworks to iron-based catalysts for the direct hydrogenation of CO2 to olefins

“…Fe 3 O 4 has been reported as the key active species for the RWGS reaction while Fe 5 C 2 is believed as the active species for the F–T reaction. 20–22 However, the relatively high reaction temperature during CO 2 hydrogenation weakens the chain growth probability and light olefins are usually obtained with poor stability over iron-based catalysts. 23–27 The design of a highly stable iron-based catalyst for efficient activation and effective control of the directional conversion of CO 2 is the key among scientific communities in CO 2 hydrogenation reactions.…”

Glucose-Induced Monodisperse Iron Oxide/Graphene Oxide Catalysts for Efficient Fischer–Tropsch Synthesis

“…25 It has been reported that the pretreatment atmosphere and the intrinsic nature of the precursors would both affect the carbide formation. 26,27 According to the above discussions, it is considered that the glucose-induced carbon-rich atmosphere will benefit the reduction and carburization behaviors of iron oxide/graphene oxide catalysts. Various characterizations including transmission electron microscopy (TEM), X-ray diffraction (XRD), N 2 physisorption, X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), thermogravimetric analysis (TGA), and Mossbauer spectroscopy were applied to investigate the effect of glucose content on the structure and property of catalysts.…”

“…The reduced state precursors will directly react with the carbon source. , It has been widely acknowledged that the Fe-based catalysts are usually coated with an amorphous carbon layer during FTS, which facilely induces the carbide transformation. , Recently, Li’s group have reported that the confinement of graphene layers favor the formation of ε-Fe 2 C from α-Fe . It has been reported that the pretreatment atmosphere and the intrinsic nature of the precursors would both affect the carbide formation. , According to the above discussions, it is considered that the glucose-induced carbon-rich atmosphere will benefit the reduction and carburization behaviors of iron oxide/graphene oxide catalysts. Various characterizations including transmission electron microscopy (TEM), X-ray diffraction (XRD), N 2 physisorption, X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), thermogravimetric analysis (TGA), and Mössbauer spectroscopy were applied to investigate the effect of glucose content on the structure and property of catalysts.…”