Phase diagram and electrical conductivity of the EuBr2–NaBr binary system

Physicochemical properties of the EuBr2–KBr binary system

“…24,000 and 34,500 cm −1 for band (I) and (II), respectively. The origin of the band are the Laporte rule allowed 4f 7 → 4f 6 5d 1 transitions in the Eu(II) ion [6,11,[16][17][18][19]. Moreover, in high energetic region of the spectrum, the Br → Eu charge transfer (CT) transition can be expected.…”

Phase diagram and electrical conductivity of the CeBr3–RbBr binary system

“…In all studied systems the specific conductance decreases with increasing CeBr 3 concentration, with significantly larger conductivity changes in the alkali bromide-rich region. We had observed a similar behaviour of electrical conductivity in other lanthanide halide-alkali metal halide binary systems [7][8]19,[21][22][23][24][25][26].…”

Thermal and conductometric studies of the CeBr3–MBr binary systems (M=Li, Na)

“…In both studied systems the specific conductivity decreases with increase of CeBr 3 concentration, with significantly larger changes in the alkali bromide-rich region. We have already observed such a general tendency in previously studied lanthanide halide-alkali metal halide binary systems [19,25,26,[29][30][31][32][33]. Raman spectroscopic investigations [34] showed that octahedral LnBr 6 3− ions are formed in the LnBr 3 -MBr liquid mixtures.…”

“…The calibration procedure (experimental temperature scale and enthalpy) of the DSC 121 was performed as described previously [22]. Samples under investigation (300-500 mg) were contained in vacuum-sealed quartz ampoules.…”

“…NdBr 3 -LiBr [17], TbBr 3 -NaBr [18], LaBr 3 -LiBr [19], EuBr 2 -KBr [20], EuBr 2 -LiBr [21], EuBr 2 -NaBr [22] as well as those of pure lanthanide bromides-LaBr 3 [23] and EuBr 2 [24]. Electrical conductivity of liquid bromide systems, i.e.…”