Phase Diagram Study for the PbO-ZnO-CaO-SiO2-"Fe2O3" System in Air with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 Weight Ratios

Abstract

An experimental study on the phase equilibrium and the liquidus isotherms for the PbO-ZnO-CaOSiO 2 -"Fe 2 O 3 " system with CaO/SiO 2 in 1.1 and PbO/(CaO+SiO 2 ) in 2.4 weight ratios, respectively, was carried out in the temperature range 1100-1300ºC (1373-1573 K). High temperature phases were determined by the equilibrium-quenching method. Results are presented in the form of pseudo-ternary sections "Fe 2 O 3 "-ZnO-(PbO+CaO+SiO 2 ). X-Ray diffraction (XRD) and SEM-EDS results showed that the phase equilibria in this system are dominated by the high melting temperature spinel and zincite phases. It was observed that if the system is at a temperature below 1300ºC and the total (Fe 2 O 3 + ZnO) is greater than 20 wt%, spinel and/or zincite will be present in the slag system. As an application of the phase diagram, the liquid phase compositions below the liquidus surface were estimated, then their viscosities were calculated using FACTSage software.