In the efforts to corroborate safer environmental CO 2 mitigation strategies, herein, we elucidate engineered practices that convert the absorbed CO 2 in a solid material and its utilization in the path of product synthesis. In this way, the cheaper lime material, the primary calcium resource, when exposed to CO 2 capture, and the storage material (CO 2 CSM) prepared by using 1,2ethylenediamine and 1, 4-butanediol resulted in the formation of controlled vaterite and aragonite CaCO 3 polymorphs in their respective pure forms mediated by the functionalized CO 2 CSM. The investigation studies demonstrated that the obtained CO 2 CSM under the supercritical CO 2 state has a higher uptake and release efficiency of CO 2 equivalent to 3.730 and 3.17 mmol/g, respectively. Therefore, the conversion of raw materials depended on the amount of CO 2 CSM availed in the reaction and would be complete at the expense of supercritical CO 2 CSM in the solid-type reaction. The mechanism study explains the fundamental formation of products correlating to the amount of CO 2 CSM supplied in the reaction which would initiate the reaction, while the amine functional group of the material could stabilize and effectively control the transition of vaterite to aragonite phases of CaCO 3 . The so-obtained CaCO 3 phases were tested for their antiwear and friction stability of the lubricant 500SN; vaterite and aragonite demonstrated good reinforcement of the mechanical properties of lubricants compared to the calcite type. Therefore, this system proposes a validation platform of using sequestrated CO 2 to generate products with industrial commercialization benefits in the reinforcement of organic-based lubricants.