Phase equilibria in the system Sm–Rh–O and thermodynamic and thermal studies on SmRhO3

Jacob, Κ. T.; Gupta, Preeti; Han, Donglin; Uda, Tetsuya

doi:10.1007/s10853-014-8014-9

Cited by 4 publications

(1 citation statement)

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“…As part of systematic investigations on LnRhO 3 compounds and Ln-Rh-O phase diagrams, [10][11][12][13][14][15][16][17][18] Gibbs energy of formation of PrRhO 3 has been measured at high temperature using a solid-state electrochemical cell in the temperature range from 875 to 1325 K. The results are used to derive a host of thermodynamic properties and construct different types of phase diagrams for the system Pr-Rh-O. There is no information in the literature on thermodynamic properties of PrRhO 3 and phase relations in the ternary involving the three components.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic properties of PrRhO₃ and phase diagrams of the system Pr–Rh–O

Jacob

Muraleedharan

2019

J Am Ceram Soc

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A solid‐state electrochemical cell with yttria‐stabilized zirconia (YSZ) as the electrolyte is used to measure accurately thermodynamic properties of PrRhO3 in the range of temperature from 875 to 1325 K. The standard Gibbs energy of formation of PrRhO3 with orthorhombically distorted perovskite structure from its binary oxides β‐Rh2O3 and hexagonal Pr2O3 is given by, ΔGf)(oxo±50/Jmol-1=-67813+5.299T/K. Invoking the Newmann‐Kopp rule, the standard enthalpy of formation from elements and standard entropy of PrRhO3 at 298.15 K are evaluated: ΔHfo=-1175.53±3.26kJmol-1 and Snormalo=108.89±0.1.3J mol-1normalK-1. Phase relations in the system Pr–Rh–O at 1200 K are computed from thermodynamic data. Calorimetric data on enthalpy of formation of two intermetallic compounds are combined with the semi‐empirical model of Miedema and phase diagram to estimate Gibbs energy of formation for the intermetallics and liquid alloys. An isothermal section of ternary phase diagram, an oxygen potential‐composition diagram in 2‐D and a 3‐D chemical potential diagram for the system Pr–Rh–O at 1200 K are presented. In addition, temperature‐composition diagrams at different oxygen pressures are developed. The diagrams provide a road map for design and optimization of processing routes for catalysts based on Rh.

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