Phase equilibria of binary mixture of carbon monoxide and water at elevated temperatures and pressures

Kramberger, Boris; Markočič, Elena; Knez, Željko

doi:10.1016/j.ces.2013.05.048

Chemical Engineering Science

2013

DOI: 10.1016/j.ces.2013.05.048

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Phase equilibria of binary mixture of carbon monoxide and water at elevated temperatures and pressures

Boris Kramberger

Elena Markočič

Željko Knez

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Cited by 9 publications

(3 citation statements)

References 23 publications

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“…In the frame of our previous research [58][59][60]62], investigation of phase equilibrium for the systems gas/water and gas mixtures/water was carried out to support the hydrogen production technologies using renewable and sustainable energy resources. These data present the basis for the design and operation of the pilot plant and dissemination of the concept to the industrial scale.…”

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confidence: 99%

“…The phase equilibrium of the binary system carbon monoxide--water were measured at temperatures 323. 15 [58][59][60]. The data has been compared to the one found in the literature [61].…”

mentioning

confidence: 99%

“…Additionally, in the supercritical area, the influence of temperature on the system density is considerable. The interactions between carbon monoxide and water may also influence the solubility trend [58][59][60][61].…”

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Production of biogas by SCF technology

Knez-Hrnčič

Škerget

Knez

2016

CI&CEQ

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PRODUCTION OF BIOGAS BY SCF TECHNOLOGY Article Highlights • An overview of the state-of-the-art of hydrogen production technologies • An overview of recently published papers dealing with SCWG of model compounds • Summary of investigations on SCWG of agricultural and food processing wastes in recent 3 years • Technical requirements and fundamental studies to support gasification for hydrogen production Abstract Hydrogen is expected to become an important fuel in the long-term since in combination with fuel cells it offers the opportunity of an intrinsically clean energy supply. By application of supercritical water gasification (SCWG) concept, sustainable hydrogen can be produced from biomass and waste. This paper offers an overview of some recently published research dealing with SCWG of model compounds and a summary of the investigations on SCWG of real agricultural and food processing wastes. In the frame of our work, intense research was performed to support analyses of SCWG of glycerol and was supported by the investigation of phase equilibrium for the systems gas/water and gas mixtures/water. When glycerol/water solutions were directly injected in the reactor operating at supercritical conditions, gases with high C2+ were obtained by the reforming in supercritical water unit. To reduce the hydrocarbon concentrations and to obtain a syngas with higher CO/CO 2 ratios from a mixture of gases (H 2 , CO, CO 2 and CH 4), catalytic reactions at high pressure and temperature were introduced reflecting in an increase of the content of H 2 and CO. Solubility measurements were conducted for the binary systems of gas and water at elevated pressures and temperatures.

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mentioning

confidence: 99%

“…The phase equilibrium of the binary system carbon monoxide--water were measured at temperatures 323. 15 [58][59][60]. The data has been compared to the one found in the literature [61].…”

mentioning

confidence: 99%

See 1 more Smart Citation

Production of biogas by SCF technology

Knez-Hrnčič

Škerget

Knez

2016

CI&CEQ

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Solubility of CO in water and NaCl(aq) at high pressures

Chen,

Trusler

2024

Chemical Engineering Science

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Hydrothermal treatment of biomass for energy and chemicals

Chen

Kravanja

Knez

2016

Energy

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Phase equilibria of binary mixture of carbon monoxide and water at elevated temperatures and pressures

Cited by 9 publications

References 23 publications

Production of biogas by SCF technology

Production of biogas by SCF technology

Solubility of CO in water and NaCl(aq) at high pressures

Hydrothermal treatment of biomass for energy and chemicals

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