Ternary liquid−liquid phase equilibria were investigated at 298.15 K for hydrophilic alcohols (2-propanol/ 1-propanol) + different salts of chloride (KCl/NaCl/CaCl 2 ) + water systems. The phase-forming and salting-out capabilities of the mentioned salts were discussed by determination of both excluded effective volume and salting-out coefficient. The results showed that the salting-out capabilities of the studied salts are as follows: CaCl 2 > NaCl > KCl. The phase-forming capability of the investigated hydrophilic alcohols was discussed by using the dielectric constant and the boiling point of the alcohols. The four-parameter equation was used to fit the binodal curves data, and also the Bancroft and Othmer−Tobias equations were successfully used to correlate the tie-lines data. Correlation of the data demonstrates that the calculated method and experimental data are in good accord.