Hydraulic fracturing of unconventional
oil/gas shales has changed
the energy landscape of the U.S. Recovery of hydrocarbons from tight,
hydraulically fractured shales is a highly inefficient process, with
estimated recoveries of <25% for natural gas and <5% for oil.
This review focuses on the complex chemical interactions of additives
in hydraulic fracturing fluid (HFF) with minerals and organic matter
in oil/gas shales. These interactions are intended to increase hydrocarbon
recovery by increasing porosities and permeabilities of tight shales.
However, fluid–shale interactions result in the dissolution
of shale minerals and the release and transport of chemical components.
They also result in mineral precipitation in the shale matrix, which
can reduce permeability, porosity, and hydrocarbon recovery. Competition
between mineral dissolution and mineral precipitation processes influences
the amounts of oil and gas recovered. We review the temporal/spatial
origins and distribution of unconventional oil/gas shales from mudstones
and shales, followed by discussion of their global and U.S. distributions
and compositional differences from different U.S. sedimentary basins.
We discuss the major types of chemical additives in HFF with their
intended purposes, including drilling muds. Fracture distribution,
porosity, permeability, and the identity and molecular-level speciation
of minerals and organic matter in oil/gas shales throughout the hydraulic
fracturing process are discussed. Also discussed are analysis methods
used in characterizing oil/gas shales before and after hydraulic fracturing,
including permeametry and porosimetry measurements, X-ray diffraction/Rietveld
refinement, X-ray computed tomography, scanning/transmission electron
microscopy, and laboratory- and synchrotron-based imaging/spectroscopic
methods. Reactive transport and spatial scaling are discussed in some
detail in order to relate fundamental molecular-scale processes to
fluid transport. Our review concludes with a discussion of potential
environmental impacts of hydraulic fracturing and important knowledge
gaps that must be bridged to achieve improved mechanistic understanding
of fluid transport in oil/gas shales.