“…The phase field method has unique advantages in the simulation method of material microstructure [1] .Since there is no need to chase the interface, and it can also eliminate the restriction of long-range diffusion and long-range interaction which cannot be settled by MC method and CA method, the phase field method is rapidly becoming a very important and popular research method. It has been widely used in the field of materials, such as solidification [2] ,grain growth [3] , micro-segregation [4] , solid phase transformation [5][6] , dislocation motion and fracture [7] , Besides, its application range is still expanding. However, the process of phase field simulation is mostly concentrated on the liquid-solid phase transformation or solid-solid phase transformation alone, and the process of the real material solidification process often contains liquid-solid-solid multiple phase transformation, such as Fe-C alloy.…”