1997
DOI: 10.1007/bf02782518
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Phase formation in titanium glazes

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Cited by 8 publications
(5 citation statements)
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“…27 Al MAS NMR spectra of G2 and G3 glazes indicate that they have a fully polymerized tetrahedral framework structure. For these glazes, the only 27 Al signal detected was for AlO 4 . For G0 and G1 glazes a signal around 15 ppm indicating the presence of AlO 6 was observed probably indicating that some of the aluminum could be charge balancing some of the AlO 4 .…”
Section: Discussionmentioning
confidence: 95%
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“…27 Al MAS NMR spectra of G2 and G3 glazes indicate that they have a fully polymerized tetrahedral framework structure. For these glazes, the only 27 Al signal detected was for AlO 4 . For G0 and G1 glazes a signal around 15 ppm indicating the presence of AlO 6 was observed probably indicating that some of the aluminum could be charge balancing some of the AlO 4 .…”
Section: Discussionmentioning
confidence: 95%
“…This indicates that using the complementarity of XRD and NMR is essential so as not to get a misleading impression of the actual distribution between glassy and crystalline components. Aluminum largely acts as a network former in these glazes, with the majority of the aluminum as AlO 4 , but in some samples small amounts of AlO 6 form. The dilatometry results demonstrated good adherence of the studied glazes on the ceramic substrate.…”
Section: Discussionmentioning
confidence: 99%
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