“…As shown in Figure 1, the particle size of the Luohuang fly ash is between 0.5 and 400 µm, with D 50 (medium diameter) of 50.7 µm, D 10 of 6.10 µm and D 90 of 178.38 µm, similar to those previously reported by Mardon et al [38], Vassilev et al [39] and Dai et al [40].…”
Section: The Particle Size Distribution Of the Fly Ashsupporting
Abstract:In order to effectively raise both utilization rate and additional value of fly ash, X-Ray diffraction (XRD), scanning electron microscope (SEM) and energy-dispersive X-Ray spectrometer (EDS) were used to investigate the morphology, and chemical and mineral composition of the microspheres in fly ash from the Luohuang coal-fired power plant, Chongqing, southwestern China. The majority of fly ash particles are various types of microspheres, including porous microsphere, plerospheres (hollow microspheres surrounding sub-microspheres or mineral fragments) and magnetic ferrospheres. Maghemite (γ-Fe 2 O 3 ) crystals with spinel octahedron structure regularly distribute on the surfaces of ferrospheres, which explained the source of their strong magnetism that would facilitate the separation and classification of these magnetic ferrospheres from the fly ash. Microspheres in Luohuang fly ash generally are characterized by an elemental transition through their cross-section: the inner layer consists of Si and O; the chemical component of the middle layer is Si, Al, Fe, Ti, Ca and O; and the Fe-O mass (maghemite or hematite) composes the outer layer (ferrosphere). Studies on composition and morphological characteristics of microspheres in fly ash would provide important information on the utilization of fly ash, especially in the field of materials.
“…As shown in Figure 1, the particle size of the Luohuang fly ash is between 0.5 and 400 µm, with D 50 (medium diameter) of 50.7 µm, D 10 of 6.10 µm and D 90 of 178.38 µm, similar to those previously reported by Mardon et al [38], Vassilev et al [39] and Dai et al [40].…”
Section: The Particle Size Distribution Of the Fly Ashsupporting
Abstract:In order to effectively raise both utilization rate and additional value of fly ash, X-Ray diffraction (XRD), scanning electron microscope (SEM) and energy-dispersive X-Ray spectrometer (EDS) were used to investigate the morphology, and chemical and mineral composition of the microspheres in fly ash from the Luohuang coal-fired power plant, Chongqing, southwestern China. The majority of fly ash particles are various types of microspheres, including porous microsphere, plerospheres (hollow microspheres surrounding sub-microspheres or mineral fragments) and magnetic ferrospheres. Maghemite (γ-Fe 2 O 3 ) crystals with spinel octahedron structure regularly distribute on the surfaces of ferrospheres, which explained the source of their strong magnetism that would facilitate the separation and classification of these magnetic ferrospheres from the fly ash. Microspheres in Luohuang fly ash generally are characterized by an elemental transition through their cross-section: the inner layer consists of Si and O; the chemical component of the middle layer is Si, Al, Fe, Ti, Ca and O; and the Fe-O mass (maghemite or hematite) composes the outer layer (ferrosphere). Studies on composition and morphological characteristics of microspheres in fly ash would provide important information on the utilization of fly ash, especially in the field of materials.
“…There is an extensive literature concerning the determination of HAP behaviour during coal combustion (e.g. Finkelman, 1994;Vassilev et al, 2005). All these studies are based on the fact that an element is enriched in the produced fly and bottom ash due to the escape of the volatile matter during combustion.…”
“…Neki isparavaju (Br, Cl, F, Hg, I), ali većina ostaje u pepelu i to prisutna u različitim klasama krupnoće. Na osnovu opsežnih istraživanja Vassilev je došao do zaključka da se u letećim pepelima koncentrišu sledeći elementi [11,12]:…”
Section: Tabela 2 Prosečan Hemijski Sastav Letećeg Pepela [1]unclassified
“…a -alumosilikatna staklasta sfera; b -glatka alumosilikatna cenosfera; c -mehurasta alumosilikatna cenosfera; d -alumosilikatna cenosfera sa kristalima kalcita i dolomita na površini; e -kristalna struktura mulit-kristobalit-kvarc u zidu alumosilikatne cenosfere; f -alumosilikatna staklasta plerosfera, g -dermasfera (larnit prekriven alumosilikatnim staklom); h -ferosfera sa dendritičnim kristalima magnetita u alumosilikatnom staklu; i -površina ferosfere (orjentisani lanci ferospinela u staklastoj fazi); j -unutrašnja struktura ferosfere; k -alumosilikatna staklasta sfera (desno) i porozni alumosilikatni sferoid (levo); l -staklasti aglomerat; m -plagioklasni sferoid; n -gips (1), kalcit (2), kalcit prekriven Ca-Mg-Na-K fazom (3), opal (4); o -različiti tipovi čestica organskog porekla [22,5,6,12] Sferoide (slika 3 k, m) se ne moraju značajno razlikovati od sfera, ali izgledaju poroznije i mehurastije. Veličina im se kreće u opsegu 10÷80 μm.…”
Section: Sl 3 Sem Izgled čEstica Prisutnih U Letećem Pepeluunclassified
“…Some evaporate (Br, Cl, F, Hg, I), but the majority remains in the ash, and they are present in different size classes. Based on extensive research, Vassilev came to the conclusion that in the fly ash the following elements are concentrated [11,12]:…”
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