The addition of an adjoint Polyakov loop term to the action of a pure gauge theory at finite temperature leads to new phases of SU (N ) gauge theories. For SU (3), a new phase is found which breaks Z(3) symmetry in a novel way; for SU (4), the new phase exhibits spontaneous symmetry breaking of Z(4) to Z(2), representing a partially confined phase in which quarks are confined, but diquarks are not. The overall phase structure and thermodynamics is consistent with a theoretical model of the effective potential for the Polyakov loop based on perturbation theory.