In this work, alloying effects of Mn, Mo, and Cr on the phase transformation behaviors of the orthorhombic and ordered v phases in high Nb-TiAl are investigated. Modulated structures are observed in the Mn and Mo-containing alloys indicating that Mn and Mo cannot hinder the formation of the orthorhombic phase while Cr hinders the formation of the orthorhombic phase completely. For the ordered v phases, small ordered v particles are observed in the Mn-containing alloy. Though Mn cannot hinder the formation of the ordered v phases, the formation temperature of which is decreased to 600 C. No ordered v phases are observed in the Mo and Cr-containing alloys. Two percent of Mo and Cr hinder the formation of the ordered v phases completely. The stabilization effect of Mn, Mo, and Cr on bo phase is mainly a thermodynamic effect.