Mesoporous
ZnSe/ZnO heterojunctions were prepared by the in situ
thermal oxidation of ZnSe at elevated temperatures in air. The partial
replacement of selenium by oxygen in the ZnSe nanoflakes led to a
highly porous microstructure with 8.2 nm mesopores distributed fairly
uniformly within the formed heterojunction sample. The as-fabricated
mesoporous ZnSe/ZnO heterojunction-based sensor exhibits an approximately
7.3-fold significantly higher response than those of both pristine
ZnO- and ZnSe-based sensors when exposed to 8 ppm NO2 at
200 °C. This sensor also demonstrates excellent selectivity for
methanol, ethanol, acetone, benzene, methylbenzene, ammonia, and formaldehyde.
The significantly enhanced response of the ZnSe/ZnO-based sensor is
due to the mesoporous microstructure during thermal oxidation of ZnSe
to ZnO, yielding more active sites and the accumulation of electrons
in the ZnO nanocrystals transferred between ZnSe/ZnO interfaces.