We report structural, optical, temperature and frequency dependent dielectric, and energy storage properties of pulsed laser deposited (100) highly textured BaZr x Ti 1−x O 3 (x=0.3, 0.4 and 0.5) relaxor ferroelectric thin films on La 0.7 Sr 0.3 MnO 3 /MgO substrates which make this compound as a potential lead-free capacitive energy storage material for scalable electronic devices. A high dielectric constant of ~1400-3500 and a low dielectric loss of <0.025 were achieved at 10 kHz for all three compositions at ambient conditions. Ultrahigh stored and recoverable electrostatic energy densities as high as 214 ± 1 and 156 ± 1 J/cm 3 , respectively, were demonstrated at a sustained high electric field of ~3 MV/cm with an efficiency of 72.8 ± 0.6 % in optimum 30% Zr substituted BaTiO 3 composition.Future use of electricity generated from any renewable energy source will benefit greatly from advanced approaches to scalable capacitive energy storage module with a favorable figure for the power-to-mass ratio (specific power) including its usage in personal electronics,