PHENACYL AND p-BROMOPHENACYL ESTERS OF MONOSUBSTITUTED BENZOIC ACIDS<sup>1</sup>

Kelly, Timm L.; Howard, Hartley W.

doi:10.1021/ja01350a037

Cited by 6 publications

(3 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For stability of the temperature controller used for data collection, see: Cosier & Glazer (1986). For the synthetic procedure, see: Kelly & Howard (1932). Hydrogen-bond geometry (Å , ).…”

Section: Related Literaturementioning

confidence: 99%

“…The title compound was synthesized according to the method reported in the literature (Kelly & Howard, 1932). A mixture of 4-bromo benzoic acid (1.0 g, 0.0049 mol), sodium carbonate (0.579 g, 0.0054 mol) and 2-bromo-1-(4-bromophenyl)ethanone (1.50 g, 0.0054 mol) in dimethyl formamide (10 ml) was stirred at room temperature for 2 h. On cooling, the separated colourless block shaped crystals of 2-(4-bromophenyl)-2-oxoethyl 4-bromobenzoate were collected by filtration.…”

Section: S2 Experimentalmentioning

confidence: 99%

See 1 more Smart Citation

2-(4-Bromophenyl)-2-oxoethyl 4-bromobenzoate

et al. 2011

View full text Add to dashboard Cite

The asymmetric unit of the title compound, C15H10Br2O3, consists of three crystallographically independent molecules (A, B and C). The phenyl rings in molecules A, B and C make dihedral angles of 6.1 (3), 3.2 (2) and 54.6 (2)° to each other, respectively. In the crystal, molecules are linked into two-dimensional layers parallel to the ab plane by intermolecular C—H⋯O hydrogen bonds. The crystal structure is further stabilized by C—H⋯π interactions. The studied crystal is an inversion twin, the refined ratio of the twin components being 0.128 (8):0.872 (8).

show abstract

“…For stability of the temperature controller used for data collection, see: Cosier & Glazer (1986). For the synthetic procedure, see: Kelly & Howard (1932). Hydrogen-bond geometry (Å , ).…”

Section: Related Literaturementioning

confidence: 99%

Section: S2 Experimentalmentioning

confidence: 99%

2-(4-Bromophenyl)-2-oxoethyl 4-bromobenzoate

et al. 2011

View full text Add to dashboard Cite

show abstract

“…For related structures, see: Fun et al (2011a,b,c). For the preparation, see: Kelly & Howard (1932).…”

Section: Related Literaturementioning

confidence: 99%

2-(4-Bromophenyl)-2-oxoethyl 4-chlorobenzoate

et al. 2011

View full text Add to dashboard Cite

show abstract

Synthese 2‐substituierter 1H‐Benz[e][1,4]oxazepin‐5‐one

Sicker

1990

J. Prakt. Chem.

View full text Add to dashboard Cite

Synthesis of 2‐Substituted 1 H‐Benz[e][1,4]oxazepin‐5‐ones An approach to the hitherto unknown class of 1H‐benz[e][1,4]oxazepin‐5‐ones is given based on reduction and cyclization of appropriate acyclic ortho‐nitro compounds as starting materials. Thus, some 2‐substituted derivatives (3a–i) were synthesized by catalytic hydrogenation of acyl 2‐nitrobenzoates (1a–i) to yield the corresponding anthranilic acid esters (2a–i), which were subsequently cyclized in polyphosphoric acid at elevated temperature. The behaviour of esters 1a–i towards spontaneous intramolecular reductive cyclization is discussed in comparison to that of similar educts leading to sixmembered heterocycles as shown by former results.

show abstract

PHENACYL AND p-BROMOPHENACYL ESTERS OF MONOSUBSTITUTED BENZOIC ACIDS¹

Cited by 6 publications

References 0 publications

2-(4-Bromophenyl)-2-oxoethyl 4-bromobenzoate

2-(4-Bromophenyl)-2-oxoethyl 4-bromobenzoate

2-(4-Bromophenyl)-2-oxoethyl 4-chlorobenzoate

Synthese 2‐substituierter 1H‐Benz[e][1,4]oxazepin‐5‐one

Contact Info

Product

Resources

About

PHENACYL AND p-BROMOPHENACYL ESTERS OF MONOSUBSTITUTED BENZOIC ACIDS1

Cited by 6 publications

References 0 publications

2-(4-Bromophenyl)-2-oxoethyl 4-bromobenzoate

2-(4-Bromophenyl)-2-oxoethyl 4-bromobenzoate

2-(4-Bromophenyl)-2-oxoethyl 4-chlorobenzoate

Synthese 2‐substituierter 1H‐Benz[e][1,4]oxazepin‐5‐one

Contact Info

Product

Resources

About

PHENACYL AND p-BROMOPHENACYL ESTERS OF MONOSUBSTITUTED BENZOIC ACIDS¹