Phenol removal from aqueous solution by adsorption and ion exchange mechanisms onto polymeric resins

Caetano, Michelle L.; Valderrama, César; Farrán, Adriana; Cortina, José Luis

doi:10.1016/j.jcis.2009.06.062

Cited by 196 publications

(105 citation statements)

References 36 publications

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“…Phenol produces harmful effects on human and animal health and aquatic ecosystems even at low concentrations. Due to its acute toxicity and good solubility and potentially carcinogenic effect, phenolic compounds are considered highpriority contaminants [1,2] . Several methods have been proposed for treating wastewater containing phenol and its derivatives.…”

Section: Introductionmentioning

confidence: 99%

Removal of Phenol from Aqueous Solutions by Polymeric Composites Containing Ni and Co Particles

Simplício¹,

Maria²,

Costa³

et al. 2013

Polímeros

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Abstract:Magnetic composites have a wide range of potential technological applications; however the evaluation of this material for extraction of phenolic compounds has not been sufficiently studied. Due to its high toxicity and solubility the removal of phenolic compounds from the aquatic environments has critical importance. In this work polymeric composites were prepared by anchoring Ni and Co particles on sulfonatedpoly(styrene-co-divinylbenzene) PS-DVB. The PS-DVB beads were synthesized by suspension polymerization and reacted with acetyl sulfate, aiming to obtain sulfonated copolymers. All materials were capable of removing phenol from aqueous solutions. The phenol adsorption kinetics was influenced by the polymer porosity and swelling capacity in water. The composite derivative of the more porous copolymer impregnated with nickel (C1SNi) was the most efficient in phenol removal, with the sorption equilibrium being established more rapidly than for the other composites. The pseudo second-order model was more adequate to describe the phenol adsorption process for the composite C1SNi. The Langmuir model describes successfully the phenol removal by this composite.

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Section: Introductionmentioning

confidence: 99%

Removal of Phenol from Aqueous Solutions by Polymeric Composites Containing Ni and Co Particles

Simplício¹,

Maria²,

Costa³

et al. 2013

Polímeros

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“…Treatment of wastewater containing phenol has been studied by various methods such as oxidation with ozone/hydrogen peroxide (Esplugas et al 2002), biological methods (Ehrhardt and Rehm 1985), ion exchange ), electrochemical oxidation (Ajeel et al 2017;Zaky and Chaplin 2014), reverse osmosis (Li et al 2017), photocatalytic degradation (Koyama et al 1994), coagulation flocculation (Yang et al 2015), and adsorption (Caetano et al 2009;Gupta et al 2004;Jain et al 2004;Ingole and Lataye 2013;Ingole et al 2017;Dhorabe et al 2016aDhorabe et al , 2016b, as well as their combinations. The majority of these methods have shown relatively low efficiency (4.5-303 mg g -1…”

Section: Introductionmentioning

confidence: 99%

“…In this framework, activated carbon (Dabrowski et al 2005;Ö zkaya 2006;Kumar et al 2007;Din et al 2009;Kilic et al 2011;Dhorabe et al 2016a;Ingole and Lataye 2013;Ingole et al 2017;Sáenz-Alanís et al 2017;Lorenc-Grabowska 2016;Srivastava et al 2006) is still the most widely used material, although it has disadvantages, such as high initial cost, high regeneration cost, and the generation of carbon fines, due to its brittle nature. Alternative adsorbents include naturally occurring materials such as different powder-based earth minerals (zeolite, bentonite, clinoptilolite) (Banat et al 2000;Mangrulkar et al 2008;Sprynskyy et al 2009), polymeric resins (Caetano et al 2009;Lin and Juang 2009;Juang and Shiau 1999;Li et al 2002;Vázquez et al 2007), polysaccharides (chitin, chitosan) (Li et al 2009;Dursun and Kalayci 2005;Ahmaruzzaman and Sharma 2005), or other inexpensive and renewable biomassresource materials (coconut shell, rice husk, ash, beet pulp etc.) (Din et al 2009;Ahmaruzzaman 2005;Chaudhary and Balomajumder 2014;.…”

Section: Introductionmentioning

confidence: 99%

In-situ synthesised hydroxyapatite-loaded films based on cellulose nanofibrils for phenol removal from wastewater

2017

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Phenol removal from aqueous medium was studied by the batch method using novel and fully biobased solvent-cast films prepared from cellulose nanofibrils (CNFs) and in situ synthesised hydroxyapatite (HAp) by the wet-chemical precipitation method and different concentrations of HAp precursors and weight mass of CNFs. The chemical and morphological structures of as-prepared films were investigated by X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy, while their physical properties were determined by water contact angle and swelling kinetic measurements. The HAp precursor leads to a surface modification of CNFs, which increases its activity by forming differently structured, sized and distributed HAp particles, influencing the phenol adsorption kinetic and capacity. The phenol adsorption was faster and higher (*64 mg g -1 ) in an acidic solution (pH 2) compared to the original phenol solution pH (pH 7.4, *30 mg g -1 ) using films with unevenly-distributed and positively-charged calcium-richer HAp particles synthesised on the CNFs' surface, being reflected also in its higher water swelling properties, compared to their hybrid counterparts. The phenol adsorption is identified to follow pseudo-second order kinetic and intra-particle diffusion models. A highly-efficient reusing ability of the selected film with 86% adsorption capacity of the initial value at the third sequential regeneration cycle, is also confirmed. A super-hydrophilic nature of the films with high water-diffusing and transport properties, as well as low swelling, indicates their potential in the development of highlyeffective adsorbents and, potentially, filter membranes for water purification.

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“…Adsorption using activated charcoal 1 , modified bentonite 2 , polymeric resins and many others 3 are the methods most frequently applied for the removal of phenols. Among the various methods membrane techniques 4 -6 and liquid-liquid extraction 5,7,8 are also often used for the purification of phenolic wastewaters.…”

Section: Introductionmentioning

confidence: 99%

Removal of phenols from aqueous solutions with solvating extractants

Regel‐Rosocka

Wiśniewski

2010

Polish Journal of Chemical Technology

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The removal of selected phenols (phenol, 4-methoxyphenol, 4-fluorophenol, 4-nitrophenol, 4-methylphenol, 4-chlorophenol, 2,4-dichlorophenol) from aqueous streams by liquid-liquid extraction is studied. Butylene and propylene carbonate -are used as green extractants. They permit to remove almost 100% of the examined phenols from feed solutions of phenol concentration about 20 g/dm 3 . Additionally, stripping of phenols from loaded organic phases is carried out with NaOH. The results of extraction parameters for alkylene carbonates (extraction efficency and distribution ratio) are compared with commercial solvating extractant -Cyanex 923.

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Phenol removal from aqueous solution by adsorption and ion exchange mechanisms onto polymeric resins

Cited by 196 publications

References 36 publications

Removal of Phenol from Aqueous Solutions by Polymeric Composites Containing Ni and Co Particles

Removal of Phenol from Aqueous Solutions by Polymeric Composites Containing Ni and Co Particles

In-situ synthesised hydroxyapatite-loaded films based on cellulose nanofibrils for phenol removal from wastewater

Removal of phenols from aqueous solutions with solvating extractants

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