Phenyl Trifluorovinyl Sulfide: A Radical Acceptor for Preparation of gem‐Difluoromethylene Compounds.

Abstract

Halogen compoundsHalogen compounds Q 0090 Phenyl Trifluorovinyl Sulfide: A Radical Acceptor for Preparation of gem-Difluoromethylene Compounds. -The synthesis of the new radical acceptor (III), its oxidation to (IV), reaction with alkyl radicals and oxidation with subsequent Pummerer reaction of the radical adducts are reported. -(OKANO*, T.; CHOKAI, M.; HIRAISHI, M.; YOSHIZAWA, M.; KUSUKAWA, T.; FUJITA, M.; Tetrahedron 60