Phenyliodine(III)diacetate (PIDA): Applications in Rearrangement/Migration Reactions

Varala, Ravi; Alam, Mohammed Mujahid; Babu, B. Hari; Amanullah, Md.; Hussein, Mohamed

doi:10.2174/1385272827666230330105241

Cited by 10 publications

(1 citation statement)

References 70 publications

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“…A thorough analysis of several synthetic methodologies that produced (CC), (CN), and (CS) bonds utilizing the I 2 /TBHP reagent system was compiled by Kapoor et al between 2010 and 2021 [14]. In keeping with our interest in investigating the uses of redox reagents [15–24], as of right now, there is not a thorough and critical evaluation of the literature on the applications of TBHP in heterocyclic ring formations. In this update, we discuss the most notable contributions of TBHP that have documented the scope of the reaction and provided mechanistic insights in heterocyclic ring formations from 2018 to date.…”

Section: Applications Of Tbhp In Heterocyclic Ring Formationsmentioning

confidence: 99%

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Varala,

Seema,

Amanullah

et al. 2024

Journal of Heterocyclic Chem

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One of the most often utilized hydroperoxides in an array of oxidation strategies is tert‐butyl hydroperoxide (tBuOOH, TBHP). The key reasons for rising utility of TBHP are its low cost, environmental friendliness, high efficiency, and ability to replace hazardous or rare heavy metal oxidants. In this sexennial update, we concisely and critically discussed the applications of TBHP in heterocyclic ring formations starting from 2018 to date. Merits and demerits of its utility, scope of a synthetic organic transformation along with mechanistic logistics are the key features of this review.

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Section: Applications Of Tbhp In Heterocyclic Ring Formationsmentioning

confidence: 99%

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Varala,

Seema,

Amanullah

et al. 2024

Journal of Heterocyclic Chem

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Decennary Update on Oxidative‐Rearrangement Involving 1,2‐Aryl C−C Migration Around Alkenes: Synthetic and Mechanistic Insights

Kumar

2024

Chemistry An Asian Journal

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In recent years, numerous methodologies on oxidative rearrangements of alkenes have been investigated, that produce multipurpose synthons and heterocyclic scaffolds of potential applications. The present review focused on recently established methodologies for oxidative transformation via 1,2‐aryl migration in alkenes (2013‐2023). Special emphasis has been placed on mechanistic pathways to understand the reactivity pattern of different substrates, challenges to enhance selectivity, the key role of different reagents, and effect of different substituents, and how they affect the rearrangement process. Moreover, synthetic limitations and future direction also have been discussed. We believe, this review offers new synthetic and mechanistic insight to develop elegant precursors and approaches to explore the utilization of alkene‐based compounds for natural product synthesis and functional materials.

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tert‐Butyl Hydroperoxide (TBHP): Recent Progress in C−H Functionalization and Heteroatom‐Heteroatom Bond Formations

Varala,

Seema,

Hussein

et al. 2024

ChemistrySelect

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Abstracttert‐Butyl hydroperoxide (tBuOOH, TBHP) is a commonly used hydroperoxide in many oxidation processes. The primary factors contributing to the increasing usefulness of TBHP include its affordability, eco‐friendliness, exceptional efficacy, and capacity to substitute harmful or rare heavy metal oxidants. In this sexennial update, we thoroughly and critically examined the most noteworthy applications of TBHP in C−H functionalization and heteroatom‐heteroatom bond formation reactions from 2018 till the present. The review has been subdivided based on the nature of the bonds being formed. The review focuses on the advantages and disadvantages of using synthetic organic transformations, as well as the breadth of their use and the underlying mechanisms involved.

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Phenyliodine(III)diacetate (PIDA): Applications in Rearrangement/Migration Reactions

Cited by 10 publications

References 70 publications

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Recent advances in TBHP‐promoted heterocyclic ring construction via annulation/cyclization

Decennary Update on Oxidative‐Rearrangement Involving 1,2‐Aryl C−C Migration Around Alkenes: Synthetic and Mechanistic Insights

tert‐Butyl Hydroperoxide (TBHP): Recent Progress in C−H Functionalization and Heteroatom‐Heteroatom Bond Formations

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