1990
DOI: 10.1055/s-1990-27033
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Phenyltrimethylammonium Tribromide for Selective Oxidation of Sulfides to Sulfoxides. A Convenient Synthesis of Sulfinyl-18O-Labelled Sulfoxide Carboxylic Acids

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Cited by 30 publications
(6 citation statements)
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“…This shelf-stable PTAB reagent has been used for the selective oxidation of sulfides to sulfoxides. 42 In conclusion, arylmercaptans and diaryl disulfides were synthesized via 3-(arylmercapto)propionic acid intermediates in good yields. The availability of aryl iodides and reagents used, coupled with easy product isolation, make these synthetic methods attractive.…”
Section: Table 2 Synthesis Of 3-(arylthio)propionic Acidsmentioning
confidence: 89%
“…This shelf-stable PTAB reagent has been used for the selective oxidation of sulfides to sulfoxides. 42 In conclusion, arylmercaptans and diaryl disulfides were synthesized via 3-(arylmercapto)propionic acid intermediates in good yields. The availability of aryl iodides and reagents used, coupled with easy product isolation, make these synthetic methods attractive.…”
Section: Table 2 Synthesis Of 3-(arylthio)propionic Acidsmentioning
confidence: 89%
“…A previous paper reported that phenyl trifluoromethyl sulfide (14) reacted with nitric and sulfuric acids to form 4nitro and 2,4-dinitro derivatives with the sulfur atom intact. 12 In our case, treatment of sulfide 14 with excess of mixed acid gave an oily product, in which 2,4-dinitrophenyl trifluoromethyl sulfide and sulfoxide were found to be major components.…”
Section: Methodsmentioning
confidence: 99%
“…8,9 Among the tribromides reported so far, the efficacy and versatility of cetyltrimethylammonium tribromide (CTMATB) has been reported in many important organic transformations. [10][11][12][13][14][15][16][17] Its proven mildness as a brominating reagent and versatility towards various organic substrates added to its compatibility with the aqueous media is what prompted us to choose this reagent for the present study.…”
Section: Introductionmentioning
confidence: 99%