The aim of this study is to investigate the effect of nitrate and nitrite on the weight, morphology and electrochemical properties of phosphated Zn-%12Ni electrodeposit coatings.In order to investigate phase structure and surface morphology of samples, X-ray diffraction and scanning electron microscopy were employed. In order to measure corrosion resistance behavior of the coats, Potentiostat/Galvanostat test was used. The results showed that nitrite accelerator reduces coating weight and surface porosity simultaneously obtaining by phosphating solution. Furthermore, coatings which were obtained by the nitrite accelerator had a higher corrosion resistance than that of the nitrate accelerator.