Phosphides and arsenides with the ZrFe4Si2-type structure

Jeitschko, Wolfgang; Terbüchte, Ludger J.; Reinbold, Elke J.; Pollmeier, Peter G.; Vomhof, T.

doi:10.1016/0022-5088(90)90321-a

Cited by 30 publications

(9 citation statements)

References 18 publications

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“…Ternary rare‐earth and actinoid transition‐metal phosphides prepared by the tin‐flux technique with iron and nickel as the transition‐metal components include the compounds ScFe 4 P 2 123 and ThFe 4 P 2 ,124 which crystallize with two different structure types, Th 5 Fe 19 P 12 124 and isotypic Yb 5 Ni 19 P 12 ,125 ThFe 5 P 3 ,126 La 2 Fe 25 P 12 ,127 Th 11 Ni 25 P 20 and isotypic U 11 Ni 25 P 20 ,128 Yb 9 Ni 26 P 12 ,129 and YbNi 5 P 3 129. With chromium as the transition‐metal component the compounds UCr 5 P 3 ,130 A 2 Cr 30 P 19 ( A =U and Zr),131, 132 and Zr 6 Cr 60 P 39 133 were prepared in well‐crystallized form from a tin flux.…”

Section: The Tin Fluxmentioning

confidence: 99%

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

2005

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This review highlights the use and great potential of liquid metals as exotic and powerful solvents (i.e. fluxes) for the synthesis of intermetallic phases. The results presented demonstrate that considerable advances in the discovery of novel and complex phases are achievable utilizing molten metals as solvents. A wide cross-section of examples of flux-grown intermetallic phases and related solids are discussed and a brief history of the origins of flux chemistry is given. The most commonly used metal fluxes are surveyed and where possible, the underlying principal reasons that make the flux reaction work are discussed.

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Section: The Tin Fluxmentioning

confidence: 99%

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

2005

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“…Folgende ternäre Seltenerdmetall‐ und Actinoid‐Übergangsmetall‐Phosphide mit Eisen oder Nickel als Übergangsmetallkomponente wurden aus Zinnschmelzen erhalten: ScFe 4 P 2 123 und ThFe 4 P 2 ,124 die mit zwei unterschiedlichen Strukturtypen kristallisieren, Th 5 Fe 19 P 12 124 und die isotype Verbindung Yb 5 Ni 19 P 12 ,125 ThFe 5 P 3 ,126 La 2 Fe 25 P 12 ,127 Th 11 Ni 25 P 20 und die isotype Verbindung U 11 Ni 25 P 20 ,128 Yb 9 Ni 26 P 12 129 und YbNi 5 P 3 129. Mit Chrom als Übergangsmetallkomponente wurden aus Zinnschmelzen in gut kristallisierter Form die Phosphide UCr 5 P 3 ,130 A 2 Cr 30 P 19 ( A =U und Zr)131, 132 und Zr 6 Cr 60 P 39 133 erhalten.…”

Section: Zinn Als Flussmittelunclassified

Metallische Schmelzen – Reaktionsmedien zur Präparation intermetallischer Verbindungen

2005

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Ziel dieses Aufsatzes ist es, die Vorzüge von flüssigen Metallen als Lösungsmittel bei der Synthese intermetallischer und ähnlich zusammengesetzter Verbindungen aufzuzeigen. Eine Vielzahl neuer Phasen mit zum Teil ungewöhnlichen Zusammensetzungen wurde in den letzten Jahren auf diese Weise erstmals hergestellt. Nach einem kurzen historischen Überblick werden die vorteilhaften Eigenschaften der eingesetzten Metallschmelzen (Flussmittel, Flux) für die Synthese eines breiten Spektrums von Verbindungen besprochen.

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“…[10]). While these compounds present a pronounced quasi-two-dimensional character, the pnictides crystallising in the ZrFe 4 Si 2 structure type are quasi-one-dimensional and have been poorly investigated [11,12,13]. In Fig.…”

mentioning

confidence: 99%

Ferromagnetic quantum criticality in the quasi-one-dimensional heavy fermion metal YbNi₄P₂

et al. 2011

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We present a new Kondo-lattice system, YbNi 4 P 2 , which is a clean heavy-fermion metal with a severely reduced ferromagnetic ordering temperature at T C = 0.17 K, evidenced by distinct anomalies in susceptibility, specific-heat, and resistivity measurements. The ferromagnetic nature of the transition, with only a small ordered moment of ∼ 0.05 µ B , is established by a diverging susceptibility at T C with huge absolute values in the ferromagnetically ordered state, severely reduced by small magnetic fields. Furthermore, YbNi 4 P 2 is a stoichiometric system with a quasi-one-dimensional crystal and electronic structure and strong correlation effects which dominate the low temperature properties. This is reflected by a stronger-thanlogarithmically diverging Sommerfeld coefficient and a linear-in-T resistivity above T C which cannot be explained by any current theoretical predictions. These exciting characteristics are unique among all correlated electron systems and makes this an interesting material for further in-depth investigations. arXiv:1108.4274v1 [cond-mat.str-el]

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Phosphides and arsenides with the ZrFe4Si2-type structure

Cited by 30 publications

References 18 publications

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

Metallische Schmelzen – Reaktionsmedien zur Präparation intermetallischer Verbindungen

Ferromagnetic quantum criticality in the quasi-one-dimensional heavy fermion metal YbNi₄P₂

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Phosphides and arsenides with the ZrFe4Si2-type structure

Cited by 30 publications

References 18 publications

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds

Metallische Schmelzen – Reaktionsmedien zur Präparation intermetallischer Verbindungen

Ferromagnetic quantum criticality in the quasi-one-dimensional heavy fermion metal YbNi4P2

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Ferromagnetic quantum criticality in the quasi-one-dimensional heavy fermion metal YbNi₄P₂