Phospholes and Related Compounds

Matano, Yoshihiro

doi:10.1002/9781118858981.ch16

Organic Redox Systems 2015

DOI: 10.1002/9781118858981.ch16

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Phospholes and Related Compounds

Yoshihiro Matano

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2017

2024

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Cited by 2 publications

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Probing the Electron Accepting Ability of Phosphaphenalenes

Zhao,

Liang,

et al. 2024

Chemistry A European J

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Phosphaphenalenes, extended π conjugates with the incorporation of phosphorus, are attractive avenues towards molecular materials for the applications in organic electronics, but their electron accepting ability have not been investigated. In this study, we present systematic studies on the reductive behavior of a representative phosphaphenalene and its oxide by chemical and electrochemical methods. The chemical reduction of the phosphaphenalene by alkali metals reveals the facile P‒C bond cleavage to form phosphaphenalenide anion, which functions as a transfer block for structure modification on the phosphorus atom. In contrast, the pentavalent P‐oxide reacts with one or two equivalents of elemental sodium to form stable radical anion and dianion salts, respectively.

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Probing the Electron Accepting Ability of Phosphaphenalenes

Zhao,

Liang,

et al. 2024

Chemistry A European J

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DFT study of host-dopant systems of DPVBi with organophosphorus π-conjugated materials

Valaboju

Gunturu

Bhanuprakash

et al. 2017

Computational and Theoretical Chemistry

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Phospholes and Related Compounds

Cited by 2 publications

References 112 publications

Probing the Electron Accepting Ability of Phosphaphenalenes

Probing the Electron Accepting Ability of Phosphaphenalenes

DFT study of host-dopant systems of DPVBi with organophosphorus π-conjugated materials

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