2018
DOI: 10.1002/ijch.201800129
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Phosphonates Meet Metal−Organic Frameworks: Towards CO2 Adsorption

Abstract: Here we report a new highly microporous zirconium phosphonate material synthesized under solvothemal conditions. The specific Brunauer-Emmett-Teller (BET) surface area of the "unconventional metalÀorganic framework" (UMOF) is measured to be~900 m 2 /g, after following an appropriate activation protocol. Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) shows that the material bears a free ÀOH functionality on the phosphonate linker that may interact with CO 2 . CO 2 adsorption isotherms were… Show more

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Cited by 6 publications
(2 citation statements)
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“…The systematic synthesis of microporous metal organic frameworks (MOFs) has spawned wide interest in early 2000s for their gas storage properties and sequestration of greenhouse gases , . As MOF research kept growing, distinct applications in diverse fields, such as catalysis, gas adsorption, drug delivery, food transportation, solar cells, conductivity, proton conductivity, biomimetic chemistry, magnetism etc., have emerged . The limitless linker geometries, possibility of attaching reactive organic functional groups around linker scaffolds have created new chemistry namely post synthetic modifications to further optimize the MOF properties .…”
Section: Introductionmentioning
confidence: 99%
“…The systematic synthesis of microporous metal organic frameworks (MOFs) has spawned wide interest in early 2000s for their gas storage properties and sequestration of greenhouse gases , . As MOF research kept growing, distinct applications in diverse fields, such as catalysis, gas adsorption, drug delivery, food transportation, solar cells, conductivity, proton conductivity, biomimetic chemistry, magnetism etc., have emerged . The limitless linker geometries, possibility of attaching reactive organic functional groups around linker scaffolds have created new chemistry namely post synthetic modifications to further optimize the MOF properties .…”
Section: Introductionmentioning
confidence: 99%
“…Gas adsorption is closely related to various aspects of human society, [98][99][100][101] such as the capture of greenhouse gas, the storage of clean fuel gases, and the trapping of toxic gases. Significantly, crystalline porous materials (especially porous metal phosphonates) are propelling the rapid development of gas adsorption due to their unprecedented surface areas, high porosities, and tunable porous structure.…”
Section: Adsorptionmentioning
confidence: 99%