Phosphoric acid-doped poly(1-vinyl-1,2,4-triazole) as water-free proton conducting polymer electrolytes

Çelik, Sevim Ünügür; Aslan, Ayşe; Bozkurt, Ayhan

doi:10.1016/j.ssi.2008.04.033

Cited by 94 publications

(93 citation statements)

References 15 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Between 3500 and 2000 cm À 1 a broadening of the band can be related to hydrogen bonding network formation. Within 1800-900 cm À 1 region, the peaks near 1100 cm À 1 and 979 cm À 1 are attributed to characteristic absorptions of the formation anion TPA as a consequence of interaction of N-H [7].…”

Section: Characterizationsmentioning

confidence: 98%

“…The homopolymer, PVTRI was reported to have a glass transition at around 165 1C [7]. Tg points of PVTRITPA blends (x¼0.…”

Section: Thermal Analysismentioning

confidence: 99%

“…A common technique used in the synthesis of anhydrous proton conducting material, namely the doping of proton solvent into the polymer matrix so that proton transport occurs almost entirely through the diffusion structure. The procedure is done through the blending of neutral/basic polymer such as with a phosphoric acid, and also by doping the acidic polymer with a heterocyclic molecule [7,8]. For a fast Grotthuss-type mechanism these must enable the formation of protonic defects and provide strongly fluctuating proton donor and acceptor functions in a polar environment [9].…”

Section: Introductionmentioning

confidence: 99%

“…In poly(4 (5)-vinylimidazole), polymer-acid complexation blocked the imidazole ring nitrogens and inhibited the structure diffusion at higher acid contents. Poly(1-vinyl-1,2,4-triazole) is a heterocyclic polymer that has three nitrogen sites per monomeric unit and showed that proton transfer is a strong contribution to proton conduction in poly(1-vinyl-1,2,4-triazole)/acid composites [7,13].…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Proton conducting composite membranes based on poly(1-vinyl-1,2,4-triazole) and nitrilotri (methyl triphosphonic acid)

Gustian

Çelik

Suratno

et al. 2011

Journal of Physics and Chemistry of Solids

View full text Add to dashboard Cite

a b s t r a c tPolymer electrolyte composite membranes based on poly(1-vinyl-1,2,4-triazole) (PVTRI) and nitrilotri(methyl triphosphonic acid) (TPA) were investigated. PVTRI was produced by free radical polymerization of 1-vinyl-1,2,4-triazole. The polymer PVTRI was doped with TPA at various molar ratios x ¼ 0.125, x ¼ 0.25, and x ¼ 0.5. The proton transfer from TPA to the triazole rings was proved with Fourier-transform infrared spectroscopy (FT-IR). Thermogravimetry (TG) analysis showed that the samples are thermally stable up to approximately 250 1C. DSC results illustrated the homogeneity of the materials as well as the softening effect of the dopant. Cyclic voltammetry results illustrated that the electrochemical stability domain of the dopant extends over 1.5 V. The maximum proton conductivity has been measured for PVTRITPA-0.25 as 8.5 Â 10 À 4 S cm À 1 at 150 1C.

show abstract

Section: Characterizationsmentioning

confidence: 98%

“…The homopolymer, PVTRI was reported to have a glass transition at around 165 1C [7]. Tg points of PVTRITPA blends (x¼0.…”

Section: Thermal Analysismentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Proton conducting composite membranes based on poly(1-vinyl-1,2,4-triazole) and nitrilotri (methyl triphosphonic acid)

Gustian

Çelik

Suratno

et al. 2011

Journal of Physics and Chemistry of Solids

View full text Add to dashboard Cite

show abstract

“…In the last decade, nitrogen-containing heterocycle compounds such as imidazole [7], benzimidazole [8,9] and triazole derivatives [10][11][12][13] have been reported to be promising protonic charge carriers in anhydrous state. Proton conduction in these systems may occur through a mechanism where protons are transferred by a hydrogen-bond breaking and forming process without the involvement of water acting as a carrier [7,14,15].…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Polymer Electrolyte Membrane based on Acid-Base Complex Pair and Its Characteristics

Gustian

Çelik

Zainuddin³

et al. 2014

j.math.fund.sci.

View full text Add to dashboard Cite

Abstract. In this work, acid-base complex pair polymer electrolyte membranes on sulfonated polysulfone with 1H-benzotriazole were investigated. Polysulfone was sulfonated in 1,2-dichloroethane using the homogeneous method with trimethylsilyl chlorosulfonate as sulfonating agent. The monomer mole ratio between polysulfone and trimethysilyl chlorosulfonate was 1:1.5. The sulfonated polysulfone was added with 1H-benzotriazole at mole ratios of x = 0.5 and x =1. The proton transfer from 1H-benzotriazole to the sulfonated polysulfone was measured using FTIR. Thermo-gravimetry analysis showed that the samples were thermally stable up to approximately 250°C and the maximum proton conductivity was found to be 3.34 x 10 -4 S cm -1 at 150°C.

show abstract

An Emerging Solid‐State Electrolyte Reactor to Drive the Future of Electrochemical Synthesis

Li,

Zhai,

Xia

et al. 2024

Advanced Energy Materials

View full text Add to dashboard Cite

Electrochemical reactors, powered by renewable electricity, have garnered widespread attention for chemical synthesis due to their low energy consumption and pollution‐free features. However, the inherent design flaw of traditional electrochemical reactors has persistently hindered the advancement of electrochemical synthesis, as they result in low product concentrations, low purity, and continuous production issues. As a novel electrochemical reactor, the porous solid‐state electrolyte (PSE) reactor is elaborately designed to overcome the limitation by enabling the direct and continuous synthesis of pure products, possessing a modular and scalable structure with high efficiency, safety, and long stability. In this work, first, the distinctive design of the PSE reactor, highlighting its structural features, core components, and variable configurations, is introduced. Furthermore, the configuration‐relevant applications in electrosynthesis, such as formic acid, acetic acid, and hydrogen peroxide (H2O2) production, are summarized. Integrated applications are also discussed, along with potential domains for improvements and optimization. Finally, the future developmental directions of the PSE devices are thoroughly explored. By addressing its unique design attributes, showcasing its capabilities, and envisioning prospective refinements and diverse applications, the aim is to boost the progression of this transformative technology toward widespread commercialization and industrial adoption, thereby revolutionizing sustainable electrochemical synthesis.

show abstract

Phosphoric acid-doped poly(1-vinyl-1,2,4-triazole) as water-free proton conducting polymer electrolytes

Cited by 94 publications

References 15 publications

Proton conducting composite membranes based on poly(1-vinyl-1,2,4-triazole) and nitrilotri (methyl triphosphonic acid)

Proton conducting composite membranes based on poly(1-vinyl-1,2,4-triazole) and nitrilotri (methyl triphosphonic acid)

Synthesis of Polymer Electrolyte Membrane based on Acid-Base Complex Pair and Its Characteristics

An Emerging Solid‐State Electrolyte Reactor to Drive the Future of Electrochemical Synthesis

Contact Info

Product

Resources

About