-Preliminary studies of photonic crystal fibers (PCFs) partially infiltrated with photo-aligned ferroelectric liquid crystals (FLCs) under the influence of external electric field are reported. The proper alignment of the FLC molecules is achieved by generating a photo-aligning layer on the inner side of the PCF microcavities. The sulfonic azo dye, which is used as an alignment layer, offers a variable anchoring energy depending on the irradiation energy, and thus, a good control on the FLC alignment inside microchannels is possible. Moreover, a state of polarization of the light being guided inside the PCF infiltrated selectively with FLC changes under the influence of external electric field.