Photo-induced synthesis of polymeric nanoparticles and chemiluminescent degradable materials <i>via</i> flow chemistry

Holloway, Joshua O.; Delafresnaye, Laura; Cameron, Emily M.; Kammerer, Jochen A.; Barner-Kowollik, Christopher

doi:10.1039/d4mh00106k

Mater. Horiz.

2024

DOI: 10.1039/d4mh00106k

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Photo-induced synthesis of polymeric nanoparticles and chemiluminescent degradable materials via flow chemistry

Joshua O. Holloway,

Laura Delafresnaye,

Emily M. Cameron

et al.

Abstract: We report the photo-induced, additive-free, continuous synthesis of polymeric particles using flow chemistry. Not only can these particles be formed under ambient conditions in a solely light induced precipitation polymerisation,...

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Cited by 3 publications

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Uniform Polymer Microspheres by Photoinduced Metal‐Free Atom Transfer Radical Precipitation Polymerization

Bicak,

Liu,

Haupt

et al. 2024

Macromol. Rapid Commun.

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Herein, a photoinduced method is introduced for the synthesis of highly cross‐linked and uniform polymer microspheres by atom transfer radical polymerization (ATRP) at room temperature and in the absence of stabilizers or surfactants. Uniform particles are obtained at monomer concentrations as high as 10% (by volume), with polymers being exempt from contamination by residual transition metal catalysts, thereby overcoming the two major longstanding problems associated with thermally initiated ATRP‐mediated precipitation polymerization. Moreover, the obtained particles have also immobilized ATRP initiators on their surface, which directly enables the controlled growth of densely grafted polymer layers with adjustable thickness and a well‐defined chemical composition. The method is then employed successfully for the synthesis of molecularly imprinted polymer microspheres.

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Uniform Polymer Microspheres by Photoinduced Metal‐Free Atom Transfer Radical Precipitation Polymerization

Bicak,

Liu,

Haupt

et al. 2024

Macromol. Rapid Commun.

View full text Add to dashboard Cite

show abstract

Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation

Wang,

Xu,

Qiu

et al. 2024

Chin J Polym Sci

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Efficient synthesis of narrow or monodisperse, physically cross-linked, and “living” spherical polymer particles via one-stage ambient temperature photoiniferter-RAFT precipitation polymerization and its particle formation mechanism

Gao,

Zhang,

Zhou

et al. 2025

Polymer

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Photo-induced synthesis of polymeric nanoparticles and chemiluminescent degradable materials via flow chemistry

Abstract: We report the photo-induced, additive-free, continuous synthesis of polymeric particles using flow chemistry. Not only can these particles be formed under ambient conditions in a solely light induced precipitation polymerisation,...

Cited by 3 publications

References 44 publications

Uniform Polymer Microspheres by Photoinduced Metal‐Free Atom Transfer Radical Precipitation Polymerization

Uniform Polymer Microspheres by Photoinduced Metal‐Free Atom Transfer Radical Precipitation Polymerization

Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation

Efficient synthesis of narrow or monodisperse, physically cross-linked, and “living” spherical polymer particles via one-stage ambient temperature photoiniferter-RAFT precipitation polymerization and its particle formation mechanism

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