Nanoplastics
(NPs) have different colors, which could affect their
photoaging processes in aquatic environments. This study investigated
the effects of irradiation on physicochemical properties and aggregation
kinetics of five colored NPs. Photodegradation rates and photooxidation
degrees ranked white ≈ yellow > red > blue ≈ black
NPs,
indicating that NPs with longer color wavelengths photoaged faster.
The discoloration process followed color fading (2–14 days,
except for white NPs), yellowing (10–16 days), yellow fading
(18 days), and turning transparent (20–22 days). White NPs
exhibited a different photoaging sequence (C–H → C–OH
→ CO → O–CO) from others. Photodegradation
was mainly controlled by singlet oxygen, producing 13 chemicals that
were mostly organic acids. The overall colloidal stability of pristine
NPs ranked blue > yellow > red > black > white. Irradiation
for 16
days retarded aggregation of white and other NPs in NaCl solution,
raising the critical coagulation concentration (CCC) by 82.14 and
0.85–7.90%, respectively. Contrarily, irradiation promoted
aggregation in CaCl2 solution by reducing the CCC of white
(67.37%) and other (33.33–37.58%) NPs. The findings demonstrate
that colored NPs underwent photoaging processes different from white/transparent
NPs, which were focused by previous work, highlighting the important
role of color in their environmental fate and transport.