A new composite photocatalyst AgBr/BiOBr was prepared by loading AgBr on a BiOBr substrate via deposition-precipitation and characterized by X-ray diffraction, scanning electron microscopy, high-resolution transmission electron microscopy and UV-vis diffuse reflectance spectroscopy. The as-prepared AgBr/BiOBr comprised face-centered cubic AgBr and tetragonal BiOBr particles. The average crystalline sizes of AgBr in the AgBr/BiOBr composites were less than 28.5 nm. The absorption edges of AgBr/ BiOBr in visible-light region had a red shift with increasing AgBr content. Photocatalytic degradation of methyl orange results show that the AgBr/BiOBr composites could degrade methyl orange efficiently under visible-light irradiation (>420 nm). The optimal molar percentage of AgBr was 50 mol% with corresponding maximum k app of 0.00619 min 1 . Active ·O 2 played a major role for methyl orange degradation while h + and ·OH had little effect on the photocatalytic process. The enhancement of photocatalytic activity of AgBr/BiOBr is mainly ascribed to the heterojunction effect between AgBr and BiOBr. [28] and WO 3 /BiOCl [29]. The synthesis of BiOX-based composites is very important for the development of highly efficient visible light photocatalysts.AgBr is an important semiconductor widely used as a photosensitive material in photography and as a photocatalyst for the degradation of pollutants or destruction of bacteria [24,[30][31][32][33][34][35][36][37][38][39][40][41][42][43][44]. Compared with BiOBr [18], AgBr [45] has a narrower band gap and higher visible-light absorption. Moreover, the two materials have matching energy band structures, according to the data reported in the literature [18,44], and which can effectively separate photogenerated electrons and holes to achieve enhanced photoactivity