2020
DOI: 10.1016/j.ccr.2020.213262
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Photocatalytic CO2 reduction over metal-organic framework-based materials

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Cited by 526 publications
(248 citation statements)
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“…To address these issues, metal-organic frameworks (MOFs), bene ting from their porous feature, ordered structure and molecular tunability, have been widely used to mediate photocatalytic CO 2 reduction. [4][5][6][7][8][9][10][11][12][13][14][15][16][17][18] In this eld, Lin et al, 16 incorporated Re(CO) 3 (bpy)Cl (bpy = bipyridine) modules into the UiO-67 framework, achieving a total turnover number (TON) of 10.9 in photocatalytic CO 2 -to-CO conversion. Wang et al achieved a high TON of 450 by using a Co-based zeolitic imidazolate framework as the cocatalyst in the presence of [Ru(bpy) 3 ] 2+ photosensitizer (PS).…”
Section: Introductionmentioning
confidence: 99%
“…To address these issues, metal-organic frameworks (MOFs), bene ting from their porous feature, ordered structure and molecular tunability, have been widely used to mediate photocatalytic CO 2 reduction. [4][5][6][7][8][9][10][11][12][13][14][15][16][17][18] In this eld, Lin et al, 16 incorporated Re(CO) 3 (bpy)Cl (bpy = bipyridine) modules into the UiO-67 framework, achieving a total turnover number (TON) of 10.9 in photocatalytic CO 2 -to-CO conversion. Wang et al achieved a high TON of 450 by using a Co-based zeolitic imidazolate framework as the cocatalyst in the presence of [Ru(bpy) 3 ] 2+ photosensitizer (PS).…”
Section: Introductionmentioning
confidence: 99%
“…Sunlight‐driven photocatalytic CO 2 reduction reactions can not only reduce the green‐house effect but also relieve the energy shortage. [ 38,117‐119 ] MOFs have recently emerged as photo‐catalytic materials for CO 2 reduction because of their fascinating features, such as abundant CO 2 adsorption sites and tunable pore sizes. [ 120‐122 ] MOFs could either serve as the photoactive materials or co‐catalysts for CO 2 reduction.…”
Section: Conversion Of Co2 To Small‐molecule Compoundsmentioning
confidence: 99%
“…The main potentials of a range of CO 2 reduction products are listed in Table 1 , which are referred the normal hydrogen electrode (NHE) at pH 7, namely E 0 V versus NHE at pH 7. [ 47–49 ]…”
Section: Fundamentals Of Porous Materials For Co2 Photoreductionmentioning
confidence: 99%