Silver nanoparticles (AgNPs) have received a lot of interest for their several applications, including their remarkable potential as photocatalysts for organic dye degradation. This research thoroughly investigates the efficacy of ecologically friendly, green-synthesized AgNPs in the treatment of synthetic dye-contaminated wastewater. The synthesis of AgNPs from various biological substrates is investigated, emphasizing their economic viability, significant conductivity, and considerable biocompatibility. The improper disposal of synthetic dyes in wastewater poses severe environmental and health risks due to their non-biodegradable nature and persistent chemical features. In response to this challenge, this review paper investigates the capability of AgNPs to serve as effective photocatalysts for degrading a range of organic dyes commonly found in industrial effluents. Specific dyes, including Aniline Blue, Congo Red, Nitrophenol, Methylene Blue, and Malachite Green, are studied in the context of wastewater treatment, providing insights into the efficacy of AgNPs synthesized from diverse biological sources. The review sheds light on the photocatalytic degradation methods used by green-synthesized AgNPs, shedding light on the transition of these synthetic dyes into less hazardous compounds. It also delves into the toxicity aspect of the AgNPs and its possible remediation from the environment. The ecologically friendly synthesis procedures investigated in this work provide an alternative to traditional methods, highlighting the importance of sustainable technologies in solving modern environmental concerns. Furthermore, a comparative examination of various biological substrates for AgNPs synthesis is presented, evaluating their respective dye degradation efficiencies. This not only helps researchers understand the environmental impact of synthetic dyes, but it also directs them in choosing the best substrates for the production of AgNPs with enhanced photocatalytic activities.