Photocatalytic degradation of phenolic pollutants over palladium-tungsten trioxide nanocomposite

N-Doped ZnWO4 Nanorods Decorated on N-Doped Reduced Graphene Oxide Sheets for Electrochemical Detection of Diphenylamine

“…The spin–orbit splitting energy of W 4f 5/2 and W 4f 7/2 is determined to be ∼2.2 eV. In comparison, for the W 4f spectrum of N-ZWR-1 sample, the peaks can be further deconvoluted into two Gaussian components with peak BEs of ∼37.7 ± 0.1 and ∼35.5 ± 0.2 eV, which are associated with the crystal lattice of W 6+ (i.e., WO 3 ) of W 4f 5/2 and W 4f 7/2 , in agreement with previous work . Notably, the BEs of W 4f were shifted to a higher BE (∼0.6 eV) in the N-ZWR-1 sample as compared to the N-ZW sample, implying a strong electronic interaction between N-ZW and N-rGO.…”