2024
DOI: 10.1002/advs.202406046
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Photocatalytic Hydrogenation of Alkenes Using Water as Both the Reductant and the Proton Source

Xinzhe Tian,
Ming Qiu,
Wankai An
et al.

Abstract: Utilization of clean and low‐cost water as the reductant to enable hydrogenation of alkenes is highly attractive in green chemistry. However, this research subject is considerably challenging due to the sluggish kinetics of the water oxidation half‐reaction. It is also very difficult to avoid the undesired oxidation of alkenes because that this oxidation is far easier to occur than the desired oxidation of water from thermodynamic standpoint. Herein, this challenge is overcome by applying a cooperative catalys… Show more

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