Photocatalytic Removal of Cr(VI) by Thiourea Modified Sodium Alginate/Biochar Composite Gel

Abstract

Heavy metal pollution is an important problem in current water treatments. Traditional methods for treating chromium-containing wastewater have limitations such as having complicated processes and causing secondary pollution. Therefore, seeking efficient and fast processing methods is an important research topic at present. Photocatalysis is an efficient method to remove Cr(VI) from aqueous solutions; however, conventional photocatalysts suffer from a low metal absorption capacity, high investment cost, and slow desorption of trivalent chromium from the catalyst surface. In this study, a novel composite gel was synthesized by chemically modifying thiourea onto sodium alginate, which was then mixed with biochar. The composite gel (T-BSA) can effectively remove 99.98% of Cr(VI) in aqueous solution through synergistic adsorption and photocatalytic reduction under UV light irradiation. The removal mechanism of Cr(VI) was analyzed by FT-IR, FESEM, UV-DRS and XPS. The results show that under acidic conditions, the amino group introduced by chemical modification can be protonated to adsorb Cr(VI) through electrostatic interaction. In addition, the biochar as a functional material has a large specific surface area and pore structure, which can provide active sites for the adsorption of Cr(VI), while the photo-reduced Cr(III) is released into the solution through electrostatic repulsion, regenerating the adsorption sites, thereby improving the removal performance of Cr(VI). Biochar significantly intensifies the Cr(VI) removal performance by providing a porous structure and transferring electrons during photoreduction. This study demonstrates that polysaccharide-derived materials can serve as efficient photocatalysts for wastewater treatment.

Adsorption of Safranin O Dye by Alginate/Pomegranate Peels Beads: Kinetic, Isotherm and Thermodynamic Studies

“…The observed peak at 1710 cm −1 in PP spectra corresponds to the C=O stretching of the aldehydes, ketones, and carbonyl groups. The peak around 1596 cm −1 and 1418 cm −1 can be assigned to the symmetric and antisymmetric stretching vibrations of COO − functional groups [75], the first one clearly overlapping δOH vibration modes of adsorbed molecules of water. The peak at 1514 cm −1 in PP and Alg−PP represents the cellulosic compounds present in the biomaterial [76].…”