Self-cleaning effect of nano-TiO 2 films have been intensively studied and widely applied in practice. In this report, nano TiO 2 materials were prepared from Titanium (IV) Tetraisopropoxide (TTIP) C 12 H 28 O 4 Ti, by sol-gel method and the thin films TiO 2 were fabricated by spin coating from TiO 2 sol on silicon wafe. The porosity and surface morphology TiO 2 thin films has been adjusted by using polyethylene glycol (PEG) at different concentration from 0% to 50%. The prepared nano TiO 2 films were mainly characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), specific surface area (BET Method) and water contact angle (WCA) measurement. Effects of the addition of PEG on the wetting performance of the resulting films were investigated. The results show that the prepared films display super-hydrophilic property when exposed to ultraviolet light and the optimal concentration of PEG was 40%. Moreover, the obtained films also exhibit considerable durability in the super-hydrophilicity when stored in the dark, which is very useful for self-cleaning application in practice.