2022
DOI: 10.21203/rs.3.rs-2112935/v1
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Photocatalyzed Regioselective Hydrosilylation for the Divergent Synthesis of Geminal and Vicinal Borosilanes

Abstract: Geminal and vicinal borosilanes are useful building blocks in synthetic chemistry and material science. Hydrosilylation/ hydroborylation of unsaturated systems offer expedient access to these motifs. In contrast to the well-established transition-metal-catalyzed methods, radical approaches are rarely explored. Herein we report the synthesis of geminal borosilanes from α-selective hydrosilylation of alkenyl boronates via photoinduced hydrogen atom transfer (HAT) catalysis. Mechanistic studies implicate that the… Show more

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