Photochemical synthesis and crystal structure of dimethylphosphinodithiatomanganese(I) tetracarbonyl, [Mn(CO)4(S2PMe2)]

Almond, Matthew J.; Drew, Michael G. B.; Sarikahya, Fadime; Şentürk, Ozan Sanlı

doi:10.1016/0277-5387(94)00416-c

Cited by 15 publications

(3 citation statements)

References 20 publications

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“…In agreement with the latter, the corresponding CÐO distances are slightly increased. Similar effects have been observed in [Mn(S 2 PEt 2 )(CO) 4 ] (Almond et al, 1995) and suggest some %-donor character of the dithiophosphinate ligand.…”

Section: Commentsupporting

confidence: 79%

Tetracarbonyl(diphenyldithiophosphinato-S,S′)rhenium(I)

Fontán¹,

Castro²,

Seoane³

et al. 2001

Acta Crystallogr C

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The title compound consists of [Re(C(12)H(10)PS(2))(CO)(4)] molecules in which the Re atom is octahedrally coordinated by four carbonyl groups and two dithiophosphinate S atoms. The main coordination distortion is imposed by the ligand bite angle of 78.29 (4) degrees. The bidentate coordination of the dithiophosphinate ligand involves almost equal Re-S [2.5366 (15) and 2.5535 (14) A] and P-S distances [2.0100 (19) and 2.0212 (19) A].

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Section: Commentsupporting

confidence: 79%

Tetracarbonyl(diphenyldithiophosphinato-S,S′)rhenium(I)

Fontán¹,

Castro²,

Seoane³

et al. 2001

Acta Crystallogr C

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“…Also the mCO modes in complexes 1 and 3 moves to lower wave numbers when compared with the starting carbonyl complexes [46,47].…”

Section: Tablementioning

confidence: 99%

Synthesis, spectroscopic characterization, thermal studies, catalytic epoxidation and biological activity of chromium and molybdenum hexacarbonyl bound to a novel N2O2 Schiff base

Aziz

2010

Journal of Molecular Structure

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“…Although a handful of Mn(I) [4][5][6][7] and Re(I) [8][9][10][11][12] complexes of dithiophosphinate ½R 2 PS 2 À ligands can be identified in the literature, yet those of their selenium analog, namely Mn/Re complexes of diselenophosphinate ½R 2 PSe 2 À have not been reported. However, some Mn and Re metallacycles formed by the chelating, selenoimidodiphosphinate ligand, N(SePPh 2 ) 2 , are known [13][14][15][16].…”

Section: Introductionmentioning

confidence: 99%