“…The photochemistry of such a sublimation-driven SO 2 atmosphere on Io is relatively straightforward, with SO 2 , SO, O, S, and O 2 being the only important photochemical products (e.g., Kumar 1982, Wong and Johnson 1996a. However, to explain the presence of the photochemically reactive S 2 molecule or alkali and halogen species in Io's atmosphere, photochemical models must also consider sputtering of surface deposits or emission from active volcanoes (e.g., Kumar 1985, Wong and Smyth 2000, Moses et al 2002. Several recent observations indicate that active volcanoes might play a larger role in controlling atmospheric properties than was previously thought.…”